Complexes of diamagnetic cations with radical anion ligands - IOPscience This site uses
cookies. By continuing to use this site you agree to our use of cookies. To find out more, see …

The chemistry of redox-active bis (imino) acenaphthenes (BIAN, R-bian) and metal
complexes based on them has been a rapidly developing field since the 1990s. The key …

The reactions of H2AlCl with [(dpp-Bian) Na (Et2O) n] and [(ArBIG-Bian) Na (THF)] produce
respective aluminum hydrides supported by radical-anionic 1, 2-bis (arylimino) …

Valence tautomerism (VT) and spin crossover (SCO) are promising avenues for developing
a range of molecular materials for sensing, memory, and optoelectronic applications …

Reactions of various substituted bis (imino) acenaphthenes (R‐BIANs) with FeCl2 (thf) 1.5
afforded the tetrahedral complexes (R‐BIAN) FeCl2 (2) from bulky α‐diimines and the …

The article examines the newly designed and structurally characterized redox-active BIAN-
derived [Ru (trpy)(R-BIAN) Cl] ClO4 ([1a] ClO4–[1c] ClO4),[Ru (trpy)(R-BIAN)(H2O)](ClO4) 2 …

To pursue a highly regioselective and efficient reductive Heck reaction, a series of moisture-
and air-stable α-diimine palladium precatalysts were rationally designed, readily …

Six ferrous chloride complexes ((Ar-BIANX) FeCl2: Ar= 2, 6-diisopropylphenyl (Dipp), X= F
(1), Cl (2), Me (3); Ar= mesityl (Mes), X= F (4), Cl (5), Me (6)) supported by sterically bulky …

A new bifunctional N4-ligand was obtained via the condensation reaction of
acenaphthenequinone and 2-picolylamine. A peculiarity of this synthesis is the formation of …

Abstract Reduction of ArBIG‐bian (1, 1, 2‐bis [(2, 6‐dibenzhydryl‐4‐methylphenyl) imino]
acenaphthene) with one molar equivalent of Li, Na or K in tetrahydrofuran (THF) affords …