Functional polymer brushes in aqueous media from self-assembled and surface-initiated polymers

R Toomey, M Tirrell - Annu. Rev. Phys. Chem., 2008 - annualreviews.org
This review focuses on the behavior of single-component, water-soluble neutral and
charged brushes. Selected examples illustrate how solvation effects, hydrophobic …

Lubrication at physiological pressures by polyzwitterionic brushes

M Chen, WH Briscoe, SP Armes, J Klein - science, 2009 - science.org
The very low sliding friction at natural synovial joints, which have friction coefficients of μ<
0.002 at pressures up to 5 megapascals or more, has to date not been attained in any …

Mixed polymer brushes with locking switching

L Ionov, S Minko - ACS applied materials & interfaces, 2012 - ACS Publications
Mixed polymer brushes, made of two different kinds of polymers randomly grafted to the
same solid substrate, were introduced as switchable interfaces for a number of promising …

Friction and normal interaction forces between irreversibly attached weakly charged polymer brushes

B Liberelle, S Giasson - Langmuir, 2008 - ACS Publications
Polyelectrolyte brushes were built on mica by anchoring polystyrene-poly (acrylic acid)(PS-b-
PAA) diblock copolymers at a controlled surface density in a polystyrene monolayer …

Macroscopic frictional properties of poly (1-(2-methacryloyloxy) ethyl-3-butyl imidazolium bis (trifluoromethanesulfonyl)-imide) brush surfaces in an ionic liquid

T Ishikawa, M Kobayashi… - ACS Applied Materials & …, 2010 - ACS Publications
Poly (1-(2-methacryloyloxy) ethyl-3-butylimidazolium bis (trifluoromethanesulfonyl)
imide)(PMIS) and poly (n-hexyl methacrylate)(PHMA) brushes were prepared on initiator …

Aqueous lubrication of poly (N-hydroxyethyl acrylamide) brushes: a strategy for their enhanced load bearing capacity and wear resistance

J Zhang, S Xiao, M Shen, L Sun, F Chen, P Fan… - RSC …, 2016 - pubs.rsc.org
Surface friction is a very important property for biomaterials, especially for those with
implantation purposes. Recently, a new hydrophilic polymer, namely, poly (N-hydroxyethyl …

Versatility of alkyne-modified poly (glycidyl methacrylate) layers for click reactions

E Soto-Cantu, BS Lokitz, JP Hinestrosa, C Deodhar… - Langmuir, 2011 - ACS Publications
Functional soft interfaces are of interest for a variety of technologies. We describe three
methods for preparing substrates with alkyne groups, which show versatility for “click” …

Normal and shear interactions between high grafting density polymer brushes grown by atom transfer radical polymerization

WP Liao, IG Elliott, R Faller, TL Kuhl - Soft Matter, 2013 - pubs.rsc.org
The normal and shear interactions in toluene of polystyrene polymer brushes with ultra-high
surface coverage ranging from 15 to 70 mg m− 2 formed by atom transfer radical …

Shape-Persistent, Thermoresponsive Polypeptide Brushes Prepared by Vapor Deposition Surface-Initiated Ring-Opening Polymerization of α-Amino Acid N …

Y Shen, S Desseaux, B Aden, BS Lokitz… - …, 2015 - ACS Publications
Surface-grafting thermoresponsive polymers allows the preparation of thin polymer brush
coatings with surface properties that can be manipulated by variation of temperature. In most …

Polymer brushes in restricted geometries

DJ Mulder, TL Kuhl - Soft Matter, 2010 - pubs.rsc.org
The structure of polymer brushes has been the subject of considerable theoretical and
experimental activity. Experimental measurements of the steric forces between grafted …