N-Heterocyclic carbene complexes in C–H activation reactions

Q Zhao, G Meng, SP Nolan, M Szostak - Chemical reviews, 2020 - ACS Publications
In this contribution, we provide a comprehensive overview of C–H activation methods
promoted by NHC–transition metal complexes, covering the literature since 2002 (the year …

Oxidative C–H/C–H coupling reactions between two (hetero) arenes

Y Yang, J Lan, J You - Chemical reviews, 2017 - ACS Publications
Transition metal-mediated C–H bond activation and functionalization represent one of the
most straightforward and powerful tools in modern organic synthetic chemistry. Bi (hetero) …

Metal-catalysed C–Het (F, O, S, N) and C–C bond arylation

B Zhao, T Rogge, L Ackermann, Z Shi - Chemical Society Reviews, 2021 - pubs.rsc.org
The formation of C–aryl bonds has been the focus of intensive research over the last
decades for the construction of complex molecules from simple, readily available feedstocks …

Oxidative coupling between two hydrocarbons: an update of recent C–H functionalizations

C Liu, J Yuan, M Gao, S Tang, W Li, R Shi… - Chemical …, 2015 - ACS Publications
C− C bond formation is a fundamental transformation in organic synthesis. The development
of new synthetic methodology could be considered as a way of pursuing a novel method for …

C–H functionalization of azines

K Murakami, S Yamada, T Kaneda, K Itami - Chemical Reviews, 2017 - ACS Publications
Azines, which are six-membered aromatic compounds containing one or more nitrogen
atoms, serve as ubiquitous structural cores of aromatic species with important applications in …

Direct (hetero) arylation polymerization: simplicity for conjugated polymer synthesis

JR Pouliot, F Grenier, JT Blaskovits, S Beaupré… - Chemical …, 2016 - ACS Publications
Direct (hetero) arylation polymerization (DHAP) has recently been established as an
environmentally benign method for the preparation of conjugated polymers. This synthetic …

Sustainable protocols for direct C–H bond arylation of (hetero) arenes

G Albano, A Punzi, MAM Capozzi, GM Farinola - Green Chemistry, 2022 - pubs.rsc.org
Direct C–H bond arylation of (hetero) arenes is a very convenient approach for the synthesis
of a wide variety of molecular targets, including compounds of pharmaceutical interest and π …

Transition Metal‐Catalyzed C H Activation of Indoles

AH Sandtorv - Advanced Synthesis & Catalysis, 2015 - Wiley Online Library
The last decades have seen a tremendous expanse in the application of C H activation of
many different substrate classes, including the invaluable indole scaffold. Following the …

Metal-free multicomponent syntheses of pyridines

C Allais, JM Grassot, J Rodriguez… - Chemical …, 2014 - ACS Publications
They react according to a succession of mono-or bimolecular processes to form at the end
one product that incorporates important portions and functionalities of the starting materials …

Recent developments in ruthenium-catalyzed C–H arylation: Array of mechanistic manifolds

P Nareddy, F Jordan, M Szostak - ACS Catalysis, 2017 - ACS Publications
Functionalized biaryl-containing motifs are among the most valuable synthetic scaffolds in
organic chemistry with wide ranging commercial applications in pharmaceuticals, functional …