Spectroscopic and theoretical investigations of vibrational frequencies in binary unsaturated transition-metal carbonyl cations, neutrals, and anions
M Zhou, L Andrews, CW Bauschlicher - Chemical Reviews, 2001 - ACS Publications
Transition-metal carbonyl complexes, M (CO) x, are cornerstones of modern coordination
chemistry and organometallic chemistry. 1 Coordinatively unsaturated transition-metal …
chemistry and organometallic chemistry. 1 Coordinatively unsaturated transition-metal …
Three coordination in metal complexes
PG Eller, DC Bradley, MB Hursthouse… - Coordination Chemistry …, 1977 - Elsevier
In this account we have attempted to review recent developments in the chemistry of three-
coordinate compounds. We have excluded from consideration the well-established …
coordinate compounds. We have excluded from consideration the well-established …
Toward reliable density functional methods without adjustable parameters: The PBE0 model
We present an analysis of the performances of a parameter free density functional model
(PBE0) obtained combining the so called PBE generalized gradient functional with a …
(PBE0) obtained combining the so called PBE generalized gradient functional with a …
A reassessment of the first metal-carbonyl dissociation energy in M (CO) 4 (M= Ni, Pd, Pt), M (CO) 5 (M= Fe, Ru, Os), and M (CO) 6 (M= Cr, Mo, W) by a quasirelativistic …
J Li, G Schreckenbach, T Ziegler - Journal of the American …, 1995 - ACS Publications
A nonlocal, quasirelativistic density functional (DF) method, NL-SCF+ QR, has been applied
to the calculation of M—CO bond lengths and the first bond dissociation energy (FBDE) in …
to the calculation of M—CO bond lengths and the first bond dissociation energy (FBDE) in …
[图书][B] Matrix Isolation: A technique for the study of reactive inorganic species
S Cradock, AJ Hinchcliffe - 1975 - books.google.com
Many chemical species are too reactive under normal conditions to allow normal
spectroscopic investigation. The technique of matrix isolation was developed to exploit the …
spectroscopic investigation. The technique of matrix isolation was developed to exploit the …
Seventeen-electron metal-centered radicals
MC Baird - Chemical Reviews, 1988 - ACS Publications
Although organotransition metal chemistry has long been dominated by compounds
containing closed-shell electron configurations and obeying the 18-electron rule, 1 there has …
containing closed-shell electron configurations and obeying the 18-electron rule, 1 there has …
[图书][B] Metal vapour synthesis in organometallic chemistry
JR Blackborow, D Young - 2012 - books.google.com
Metal Vapour Synthesis (MVS) can be defined as;" The use in synthesis of high temper ature
gaseous species such as metal atoms by their reactions with themselves or other materials …
gaseous species such as metal atoms by their reactions with themselves or other materials …
Reactions of laser-ablated Ni, Pd, and Pt atoms with carbon monoxide: matrix infrared spectra and density functional calculations on M (CO) n (n= 1− 4), M (CO) n-(n …
Laser-ablated Ni, Pd, and Pt atoms have been reacted with CO molecules followed by
condensation in excess neon at 4 K. Besides the neutral metal carbonyl species, metal …
condensation in excess neon at 4 K. Besides the neutral metal carbonyl species, metal …
New method for the determination of the geometries of binary transition metal complexes
JK Burdett - Inorganic Chemistry, 1975 - ACS Publications
A simple model based on the interaction of ligand electron pairs and holes in the central
metal charge distribution is used to rationalize the shapes of binary transition metal …
metal charge distribution is used to rationalize the shapes of binary transition metal …
Photochemistry of the Group 6 hexacarbonyls in low-temperature matrixes. IV. Tetracarbonylmolybdenum and tricarbonylmolybdenum
RN Perutz, JJ Turner - Journal of the American Chemical Society, 1975 - ACS Publications
Abstract; Uv photolysis of Mo (CO) 6 in a CH4 matrix produces Mo (CO) s and two
secondaryphotolysis products, which grow sequentially. Their spectra and growth patterns …
secondaryphotolysis products, which grow sequentially. Their spectra and growth patterns …