Hydrogen emerges as one of the cleanest and most renewable energy resources for fossil
fuel alternatives. Commercial-scale hydrogen production through water-splitting …

A newly designed copper complex of 5, 15-bis (pentafluorophenyl)-10, 20-bis (o-carborane)
porphyrin (1) was synthesized and tested for the electrocatalytic hydrogen evolution reaction …

The electronic structure of metal complexes plays key roles in determining their catalytic
features. However, controlling electronic structures to regulate reaction mechanisms is of …

Zn (II), Cu (II), and Ni (II) 5, 10, 15, 20-tetrakis (4-fluoro-2, 6-dimethylphenyl) porphyrins
(TFPs) have been synthesized and characterized. The electronic spectroscopy and cyclic …

The oxidative coupling reaction of two Ni (II) porphyrins meso‐substituted with three and four
phenyl groups, Ni (II) 5, 10, 15‐(triphenyl) porphyrin (NiPh3P) and Ni (II) 5, 10, 15, 20 …

The development of efficient molecular catalysts for the electrocatalytic hydrogen evolution
reaction (HER) is very necessary and important for fuel cells. In this work, we report a new …

The conversion of CO2 into fuels or commodity chemicals by electrochemical or
photochemical reduction is a promising strategy to relieve the ongoing energy crisis and …

In this study, we discovered the high catalytic activity of a dinuclear cobalt complex,
Co2DNCH, supported by a doubly N-confused hexaphyrin (DNCH), a kind of ring-expanded …

Three binuclear metal (M= Co, Fe, Mn) xanthine bridged bis-corrole complexes were
synthesized and investigated as electrocatalysts for the hydrogen evolution reaction (HER) …