Electro-and solar-driven fuel synthesis with first row transition metal complexes

KE Dalle, J Warnan, JJ Leung, B Reuillard… - Chemical …, 2019 - ACS Publications
The synthesis of renewable fuels from abundant water or the greenhouse gas CO2 is a
major step toward creating sustainable and scalable energy storage technologies. In the last …

New avenues for ligand-mediated processes–expanding metal reactivity by the use of redox-active catechol, o-aminophenol and o-phenylenediamine ligands

DLJ Broere, R Plessius, JI van der Vlugt - Chemical Society Reviews, 2015 - pubs.rsc.org
Redox-active ligands have evolved from being considered spectroscopic curiosities–
creating ambiguity about formal oxidation states in metal complexes–to versatile and useful …

Radical‐type reactivity and catalysis by single‐electron transfer to or from redox‐active ligands

JI van der Vlugt - Chemistry–A European Journal, 2019 - Wiley Online Library
Controlled ligand‐based redox‐activity and chemical non‐innocence are rapidly gaining
importance for selective (catalytic) processes. This Concept aims to provide an overview of …

Cooperative catalysis with first‐row late transition metals

JI van der Vlugt - European Journal of Inorganic Chemistry, 2012 - Wiley Online Library
Cooperative catalysis with first‐row transition metals holds much promise for future
developments regarding sustainable, selective transformations, including eg alkenes …

Room temperature metallic conductivity in a metal–organic framework induced by oxidation

AJ Clough, NM Orchanian, JM Skelton… - Journal of the …, 2019 - ACS Publications
Metal–organic frameworks (MOFs) containing redox active linkers have led to hybrid
compounds exhibiting high electrical conductivity, which enables their use in applications in …

Redox-active ligands for chemical, electrochemical, and photochemical molecular conversions

A Nakada, T Matsumoto, HC Chang - Coordination Chemistry Reviews, 2022 - Elsevier
A central issue in the design of reactions and catalysts based on metal complexes is the
hybridization of functional ligands with metal atoms. Recent studies have demonstrated that …

Broad electronic modulation of two-dimensional metal–organic frameworks over four distinct redox states

L Wang, A Sarkar, GL Grocke… - Journal of the …, 2023 - ACS Publications
Two-dimensional (2D) inorganic materials have emerged as exciting platforms for (opto)
electronic, thermoelectric, magnetic, and energy storage applications. However, electronic …

Novel iron (III) catalyst for the efficient and selective coupling of carbon dioxide and epoxides to form cyclic carbonates

A Buonerba, A De Nisi, A Grassi, S Milione… - Catalysis Science & …, 2015 - pubs.rsc.org
“Re-cycling carbon dioxide with iron”. The synthesis of cyclic organic carbonates in high
yield, stereo-and chemo-selectivity was accomplished through the coupling of carbon …

Concepts for metal complex chromophores absorbing in the near infrared

W Kaim - Coordination Chemistry Reviews, 2011 - Elsevier
The near-infrared (750–2500nm) region of the electromagnetic spectrum has received
enhanced attention recently from the areas of atmospheric and analytical chemistry, from …

Ammonia formation by a thiolate-bridged diiron amide complex as a nitrogenase mimic

Y Li, Y Li, B Wang, Y Luo, D Yang, P Tong, J Zhao… - Nature Chemistry, 2013 - nature.com
Although nitrogenase enzymes routinely convert molecular nitrogen into ammonia under
ambient temperature and pressure, this reaction is currently carried out industrially using the …