C Lefay, Y Guillaneuf - Progress in Polymer Science, 2023 - Elsevier
Polymers have many advantages such as low weight, low cost, and, importantly, stability under thermal, chemical, and mechanical stress. This stability, on the other hand, leads to …
We present the bulk depolymerization of poly (methyl methacrylate)(PMMA) at significantly lower temperatures than previously reported methods through the incorporation of …
A photocatalytic ATRP depolymerization is introduced that significantly suppresses the reaction temperature from 170 to 100° C while enabling temporal regulation. In the presence …
Fast bulk depolymerization of poly (n-butyl methacrylate) and poly (methyl methacrylate), prepared by atom transfer radical polymerization (ATRP), is reported in the temperature …
We establish a synthetically convenient method to degrade polyacrylate homopolymers. Carboxylic acids are installed along the polymer backbone by partial hydrolysis of the ester …
Although controlled radical polymerization is an excellent tool to make precision polymeric materials, reversal of the process to retrieve the starting monomer is far less explored …
Depolymerization of polymers synthesized by reversible deactivation radical polymerization (RDRP) has recently emerged as a promising chemical recycling method for a circular …
RW Hughes, ME Lott, IS Zastrow… - Journal of the …, 2024 - ACS Publications
In this study, we present an efficient approach for the depolymerization of poly (methyl methacrylate)(PMMA) copolymers synthesized via conventional radical polymerization. By …
T Kimura, M Ouchi - Angewandte Chemie International Edition, 2023 - Wiley Online Library
In this work, we achieved a triggering degradation of polymers composed of carbon‐carbon (C− C) bonded backbone without relying on introduction of labile heteroatom‐based bond …