Organic ferroelectrics

S Horiuchi, Y Tokura - Nature materials, 2008 - nature.com
Ferroelectricity results from one of the most representative phase transitions in solids, and is
widely used for technical applications. However, observations of ferroelectricity in organic …

Chemical design and physical properties of dynamic molecular assemblies

T Akutagawa - Bulletin of the Chemical Society of Japan, 2021 - academic.oup.com
The thermally activated motional freedom of protons (H+), ions (M+), and molecules can be
controlled using supramolecular approaches. In single crystals, motional freedom is enabled …

Proton tautomerism for strong polarization switching

S Horiuchi, K Kobayashi, R Kumai… - Nature communications, 2017 - nature.com
Ferroelectrics based on proton tautomerism are promising in low-field and above-room-
temperature operations. Here seven organic ferroelectric crystals are examined to search for …

Hydrogen-bonded small-molecular crystals yielding strong ferroelectric and antiferroelectric polarizations

S Horiuchi, S Ishibashi - Journal of the Physical Society of Japan, 2020 - journals.jps.jp
The development of organic ferroelectrics and antiferroelectrics with significantly improved
performances has recently increased. Their attractive features are environmentally benign …

Dynamics of proton, ion, molecule, and crystal lattice in functional molecular assemblies

T Akutagawa, T Takeda, N Hoshino - Chemical Communications, 2021 - pubs.rsc.org
Dynamic molecular processes, such as short-or long-range proton (H+) and ion (M+)
motions, and molecular rotations in electrical conducting and magnetic molecular …

Molecular donor–acceptor compounds as prospective organic electronics materials

S Horiuchi, T Hasegawa, Y Tokura - … of the Physical Society of Japan, 2006 - journals.jps.jp
The π-electronic functionalities of molecular donor (D)–acceptor (A) compounds have been
attracting subjects for the solid state science as well as for the prospective technological …

Dynamic molecular assemblies toward a new frontier in materials chemistry

T Akutagawa - Materials Chemistry Frontiers, 2018 - pubs.rsc.org
The crystal lattice energy of π-molecules is dominated by weak and anisotropic
intermolecular interactions ranging in energy from 1 to∼ 20 kJ mol− 1, which can be tuned …

Chemical approach to neutral–ionic valence instability, quantum phase transition, and relaxor ferroelectricity in organic charge-transfer complexes

S Horiuchi, R Kumai, Y Okimoto, Y Tokura - Chemical physics, 2006 - Elsevier
Neutral–ionic (NI) phase transition is a reversible switching of organic charge-transfer
complexes between distinct valence states by external stimuli. This phase transformation in …

Hydrogen-bonded donor–acceptor compounds for organic ferroelectric materials

S Horiuchi, R Kumai, Y Tokura - Chemical communications, 2007 - pubs.rsc.org
Organic ferroelectrics are multifunctional candidates for future organic electronic and optical
devices. In spite of their potential, only a few organic compounds are known to exhibit a …

Tautomerism in the solid state

T Sugawara, I Takasu - Advances in Physical Organic Chemistry, 1999 - Elsevier
Publisher Summary Proton tautomerism occurs readily in solution because there are no
restrictions in fluid media on the conformational changes required for the tautomerization to …