The catalytic cycloaddition of CO2 to epoxides to afford cyclic carbonates as useful
monomers, intermediates, solvents, and additives is a continuously growing field of …

Conspectus Biologically active compounds and pharmaceutically relevant intermediates
often feature sterically congested stereogenic centers, in particular, carbon stereocenters …

Enantioselective metallaphotoredox catalysis, which combines photoredox catalysis and
asymmetric transition-metal catalysis, has become an effective approach to achieve …

Due to its mild reaction conditions and unique chemoselectivity, hydrogen atom transfer
(HAT) hydrogenation represents an indispensable method for the synthesis of complex …

A new regio-and stereoselective reductive coupling of alkynes and crotononitrile has been
developed via visible light organophotoredox cobalt dual catalysis. A variety of …

Catalytic metal hydride hydrogen atom transfer (MHAT) reactions have proven to be a
powerful method for alkene functionalization. This work reports the discovery of Co …

Catalytic generation of ambiphilic π-allyl–metal complexes and their utility in
enantioselective transformations constitutes a powerful approach for introduction of allyl …

The synthesis of cyclic carbonates by cycloaddition of CO2 to epoxides is a convenient non-
reductive strategy to valorize carbon dioxide. Biphasic chemistry is an emerging and …

The catalysis by a π-allyl-Co/Ni complex has drawn significant attention recently due to its
distinct reactivity in reductive Co/Ni-catalyzed allylation reactions. Despite significant …

A visible light‐induced Co‐catalyzed highly regio‐and stereoselective reductive coupling of
vinyl azaarenes and alkynes has been developed. Notably, Hünig's base together with …