One of the attractive properties of the hollow carbon clusters, known as fullerenes, is the
possibility to use them as robust containers for other species. Although an IUPAC …

Fullerenes have the characteristic of a hollow interior, and this unique feature triggers
intuitive inspiration to entrap atoms, ions or clusters inside the carbon cage in the form of …

The Dy-Sc nitride clusterfullerene Dy2ScN@ C80-Ih exhibits slow relaxation of
magnetization up to 76 K. Above 60 K, thermally-activated relaxation proceeds via the fifth …

Nd-based nitride clusterfullerenes NdM2N@ C80 with rare-earth metals of different sizes
(M= Sc, Y, Lu) were synthesized to elucidate the influence of the cluster composition, shape …

Reducing inter-spin distance can enhance magnetic interactions and allow for the
realization of outstanding magnetic properties. However, achieving reduced distances is …

The synthesis and single‐crystal X‐ray structural characterization of the first endohedral
metallofullerene to contain a heptagon in the carbon cage are reported. The carbon …

Relaxation of magnetization in endohedral metallofullerenes DySc2N@ C80 is studied at
different temperatures, in different magnetic fields, and in different molecular arrangements …

So far the entrapped metals for the isolated endohedral metallofullerenes (EMFs) are
primarily limited to rare earth metals, whereas except group-IVB metals, whether it is …

Endohedral clusters inside metallofullerenes experience considerable inner strain when the
size of the hosting cage is comparably small. This strain can be tuned in mixed-metal …

Paramagnetic and variable temperature 13C and 45Sc nuclear magnetic resonance studies
are performed for nitride clusterfullerenes MSc2N@ C80 with icosahedral Ih (7) carbon …