Organometallic Fluorides: Compounds Containing Carbon− Metal− Fluorine Fragments of d-Block Metals

EF Murphy, R Murugavel, HW Roesky - Chemical reviews, 1997 - ACS Publications
For the purpose of this review the term organometallic fluoride is used strictly to describe
compounds containing fluorine-metal and carbon-metal bonds with the same metal atom …

Five-membered metallacycles of titanium and zirconium–attractive compounds for organometallic chemistry and catalysis

U Rosenthal, VV Burlakov, MA Bach… - Chemical Society …, 2007 - pubs.rsc.org
In these days a renaissance of metallacycles as an increasingly important class of
organometallic compounds for synthetic and catalytic applications is evident, making such …

[图书][B] Phosphorus-31 NMR spectroscopy: a concise introduction for the synthetic organic and organometallic chemist

O Kühl - 2008 - books.google.com
Nuclear Magnetic Resonance is a powerful tool, especially for the identification of 1 13
hitherto unknown organic compounds. H-and C-NMR spectroscopy is known and applied by …

Catalytic reductive ring opening of epoxides enabled by zirconocene and photoredox catalysis

K Aida, M Hirao, A Funabashi, N Sugimura, E Ota… - Chem, 2022 - cell.com
The reductive ring opening of epoxides is a powerful transformation to convert readily
accessible epoxides into a diverse array of valuable alcohols, including pharmaceuticals …

Efficient Synthesis of Chiral ansa-Metallocenes by Amine Elimination. Synthesis, Structure, and Reactivity of rac-(EBI)Zr(NMe2)2

GM Diamond, RF Jordan… - Journal of the American …, 1996 - ACS Publications
The amine elimination reaction of Zr (NMe2) 4 (2) and (EBI) H2 (1, 2-bis (3-indenyl) ethane,
3) in toluene at 100° C affords pure rac-(EBI) Zr (NMe2) 2 (rac-4, EBI= ethylene-1, 2-bis (1 …

Neutral and cationic tetracoordinated aluminum complexes featuring tridentate nitrogen donors: synthesis, structure, and catalytic activity for the ring-opening …

N Emig, H Nguyen, H Krautscheid, R Réau… - …, 1998 - ACS Publications
The dilithium salts of N, N ', N ''-tris (trimethylsilyl) diethylenetriamine (1), N-methyl-N ', N ''-bis
(trimethylsilyl) diethylenetriamine (2), and N-methyl-N ', N ''-bis (diisopropyl) …

Organozirconium complexes as catalysts for Markovnikov-selective intermolecular hydrothiolation of terminal alkynes: scope and mechanism

CJ Weiss, TJ Marks - Journal of the American Chemical Society, 2010 - ACS Publications
The efficient and selective organozirconium (IV)-mediated, intermolecular hydrothiolation of
terminal alkynes by aliphatic, benzylic, and aromatic thiols using CGCZrMe2 (CGC …

Metal-phosphido and-phosphinidene complexes in P–E bond-forming reactions

R Waterman - Dalton Transactions, 2009 - pubs.rsc.org
Metal complexes bearing terminal phosphido or phosphinidene ligands have become
versatile tools in the stoichiometric and catalytic preparation of phosphorus–element bonds …

Phosphido-and amidozirconocene cation-based frustrated Lewis pair chemistry

AT Normand, CG Daniliuc, B Wibbeling… - Journal of the …, 2015 - ACS Publications
Methyl abstraction from neutral [Cp2ZrMe (ERR′)] complexes 1 (E= N, P; R, R′= alkyl,
aryl) with either B (C6F5) 3 or [Ph3C][B (C6F5) 4] results in the formation of [Cp2Zr …

Performance of density functionals for activation energies of Zr-mediated reactions

Y Sun, H Chen - Journal of chemical theory and computation, 2013 - ACS Publications
Coupled cluster CCSD (T) calculations with core–valence correlation and complete basis
set (CBS) limit extrapolation are used to benchmark the performance of commonly used …