[HTML][HTML] Towards understanding the competition of electron and energy transfer in “molecular” nanographenes on the example of hexa-peri-hexabenzocoronene

GM Beneventi, M Krug, D Reger, N Jux… - Journal of Photochemistry …, 2023 - Elsevier
Bottom-up strategies have allowed the synthesis of “molecular” nanographenes with full
control over size, shape and functionality. In recent years, the progress on wet chemical …

Nanographene-Fused Expanded Carbaporphyrin Tweezers

H He, YJ Lee, Z Zong, N Liu, VM Lynch… - Journal of the …, 2023 - ACS Publications
A nanographene-fused expanded carbaporphyrin (5) and its BF2 complex (6) were
synthesized. Single-crystal X-ray structures revealed that 5 and 6 are connected by two hexa …

Chalcogen-doped,(seco)-hexabenzocoronene-based nanographenes: synthesis, properties, and chalcogen extrusion conversion

R Li, B Ma, S Li, C Lu, P An - Chemical Science, 2023 - pubs.rsc.org
A series of chalcogen-doped nanographenes (NGs) and their oxides are described. Their
molecular design is conceptually based on the insertion of different chalcogens into the …

Regioisomeric Benzidine‐Fullerenes: Tuning of the Diverse Hole‐Distribution to Influence Charge Separation Patterns

C Wang, B Wu, Y Li, T Dong, Y Chai… - Angewandte Chemie …, 2023 - Wiley Online Library
Understanding the influence of molecular structure on charge distribution and charge
separation (CS) provides essential guidance for optoelectronic materials design. Here we …

Uncovering the substituted-position effect on excited-state evolution of benzophenone-phenothiazine dyads

J Li, S Yang, Z Deng, A Islam, S Wu, J He… - The Journal of …, 2023 - pubs.aip.org
Photofunctional materials based on donor-acceptor molecules have drawn intense attention
due to their unique optical properties. Importantly, Systematic investigation of substitution …

InP quantum dots: Stoichiometry regulates carrier dynamics

B Manoj, D Rajan, KG Thomas - The Journal of Chemical Physics, 2023 - pubs.aip.org
The optical properties of non-toxic indium phosphide (InP) quantum dots (QDs) are
impinged by the existence of characteristic deep trap states. Several surface engineering …

Decarboxylative 1, 3-dipolar cycloaddition of amino acids for the synthesis of heterocyclic compounds

X Zhang, X Ma, W Zhang - Beilstein Journal of Organic …, 2023 - beilstein-journals.org
Abstract The [3+ 2] cycloadditions of stabilized azomethine ylides (AMYs) derived from
amino esters are well-established. However, the reactions of semi-stabilized AMYs …

Rational Construction and Efficient Regulation of Stable and Long-Lived Charge-Separation State in Fullerene Materials

C Wang, B Wu, C Wang - Accounts of Materials Research, 2024 - ACS Publications
Conspectus Photoinduced charge separation (CS) ensures efficient light-energy conversion.
The stable and long-lived charge-separation state (CSs) is beneficial for suppressing charge …

Multi-heteroatom doped nanographenes: enhancing photosensitization capacity by forming electron donor-acceptor architecture

R Li, B Ma, M Li, D Wang, P Liu, P An - Chemical Science, 2024 - pubs.rsc.org
Systematically tuning and optimizing the properties of synthetic nanographenes (NGs) is
particularly important for NG applications in diverse areas. Herein, by devising novel …

Electron-acceptor-controlled polyimides for photoredox-neutral trifluoromethylation

L Zuo, G Qiu, Y Liu, X Chen, K Sun, IB Krylov, L Qu… - Chem Catalysis, 2024 - cell.com
Heterogeneous photocatalysts present notable benefits over homogeneous systems.
However, their application is often hindered by spontaneous electron-hole recombination …