Covalent adaptable networks using β-amino esters as thermally reversible building blocks
In this study, β-amino esters, prepared by the aza-Michael addition of an amine to an
acrylate moiety, are investigated as building blocks for the formation of dynamic covalent …
acrylate moiety, are investigated as building blocks for the formation of dynamic covalent …
Endowing polythioester vitrimer with intrinsic crystallinity and chemical recyclability
Technologically important thermosets face a long‐standing end‐of‐life (EoL) problem of non‐
reprocessability, a more sustainable solution of which has resolved to nascent vitrimers that …
reprocessability, a more sustainable solution of which has resolved to nascent vitrimers that …
Polyaddition synthesis using alkyne esters for the design of vinylogous urethane vitrimers
Y Spiesschaert, J Danneels, N Van Herck… - …, 2021 - ACS Publications
Vitrimers are a subclass of covalent adaptable networks which introduce reshapeability and
recyclability in thermoset materials while maintaining a high degree of chemical resistance …
recyclability in thermoset materials while maintaining a high degree of chemical resistance …
Nanotechnology in covalent adaptable networks: from nanocomposites to surface patterning
Cross-linked polymers with dynamic covalent linkages that can exchange and/or reversibly
cleave and reformed in response to external stimuli are known as covalent adaptable …
cleave and reformed in response to external stimuli are known as covalent adaptable …
Dynamic Covalent Chemistry of Enamine‐Ones: Exploring Tunable Reactivity in Vitrimeric Polymers and Covalent Organic Frameworks
Dynamic covalent chemistry (DCC) has revolutionized the field of polymer science by
offering new opportunities for the synthesis, processability, and recyclability of polymers as …
offering new opportunities for the synthesis, processability, and recyclability of polymers as …
Biobased, creep-resistant covalent adaptable networks based on β-amino ester chemistry
L Stricker, C Taplan, FE Du Prez - ACS Sustainable Chemistry & …, 2022 - ACS Publications
For this study, creep-resistant covalent adaptable networks were prepared by making use of
the reversible β-amino ester chemical platform and starting from biobased raw materials with …
the reversible β-amino ester chemical platform and starting from biobased raw materials with …
Epoxy resin with exchangeable diselenide crosslinks to obtain reprocessable, repairable and recyclable fiber-reinforced thermoset composites
The cross-linked structure of thermosetting carbon fiber composites makes it difficult to
degrade and recycle, especially the non-destructive recovery and recycling of high value …
degrade and recycle, especially the non-destructive recovery and recycling of high value …
Reaction of β‐Ketoester and 1, 3‐Diol to Access Chemically Recyclable and Mechanically Robust Poly (vinyl alcohol) Thermosets through Incorporation of β‐(1, 3 …
The development of mechanically robust, chemically stable, and yet recyclable polymers
represents an essential undertaking in the context of advancing a circular economy for …
represents an essential undertaking in the context of advancing a circular economy for …
Facile Catalyst‐Free Approach toward Fully Biobased Reprocessable Lignin Thermosets
L Buzoglu Kurnaz, Y Bension… - … Chemistry and Physics, 2023 - Wiley Online Library
Reprocessable and biobased thermosets are prepared from two renewable feedstocks,
lignin and polyamine (Priamine 1071). Lignin is oxidized to produce polycarbonyl and …
lignin and polyamine (Priamine 1071). Lignin is oxidized to produce polycarbonyl and …
[HTML][HTML] Exploiting β-amino ester chemistry to obtain methacrylate-based covalent adaptable networks
In this study, β-amino ester-based covalent adaptable networks (CANs) were synthesised
through aza-Michael addition of amines to methacrylates, with the aim of developing …
through aza-Michael addition of amines to methacrylates, with the aim of developing …