Comprehensive Summary A photoelectrochemical approach for the C—H silylation of
heteroarenes through dehydrogenation cross‐coupling with H2 evolution has been …

Nitroaromatic compounds represent one of the essential classes of molecules that are
widely used as feedstock for the synthesis of intermediates, the preparation of nitro‐derived …

Guar gum (GG) from seeds of cluster bean (Cyamopsis tetragonolobus) contains mainly non-
ionic galactomannan polysaccharide. Due to fascinating properties, great natural …

Hydroxylated (hetero) arenes are valued in many industries as both key constituents of end
products and diversifiable synthetic building blocks. Accordingly, the development of …

Organosilicon compounds are highly important molecular scaffolds with versatile synthetic
utility, and are used in a range of transformations. Such organosilicon compounds are …

Reductive functionalization of N-heteroarenes offers a route to highly versatile heterocyclic
synthons bearing multiple transformable groups. We present herein the development of KO t …

The transition-metal-catalyzed cross-coupling of aryl halides with silylation reagents is a
powerful strategy for C (sp2)–Si bond formation. However, the need for the tedious …

Herein, we report that a cobalt catalyst permits the general synthesis of substituted
alkynylsilanes through dehydrogenative coupling of alkynylsilanes and hydrosilanes …

Aromatic organosilanes bearing C (sp2)–Si bonds have found increasing applications
across the chemical science, yet are mostly produced by atom-uneconomical stoichiometric …

Mechanisms for the Csp–H silylation between prop-2-yn-1-ylcyclohexane and triethylsilane,
catalyzed by MOH/MH (M= Na or K), were investigated at the M06-L-D3/ma-def2-TZVP level …