Magnetic pyrochlore oxides

JS Gardner, MJP Gingras, JE Greedan - Reviews of Modern Physics, 2010 - APS
Within the past 20 years or so, there has occurred an explosion of interest in the magnetic
behavior of pyrochlore oxides of the type A 2 3+ B 2 4+ O 7, where A is a rare-earth ion and …

Perspectives on pyrochlores, defect fluorites, and related compounds: building blocks for chemical diversity and functionality

GR Lumpkin, RD Aughterson - Frontiers in Chemistry, 2021 - frontiersin.org
In this article we provide some perspectives on a range of pyrochlore and defect fluorite type
compounds with nominal A2B2O7, A2BO5, ABC2O7, and other stoichiometries. Typically …

Structural properties and the fluorite–pyrochlore phase transition in La2Zr2O7: the role of oxygen to induce local disordered states

B Paul, K Singh, T Jaroń, A Roy… - Journal of Alloys and …, 2016 - Elsevier
Structural and functional applications involving La 2 Zr 2 O 7 exploit the data on fluorite to
pyrochlore phase transition, because of the strong dependence on the physical properties of …

New solid electrolytes of the pyrochlore family

AV Shlyakhtina, LG Shcherbakova - Russian Journal of Electrochemistry, 2012 - Springer
The class of oxygen-ion-conducting rare-earth pyrochlores has been considerably
extended. New solid electrolytes, Ln 2 Ti 2 O 7 (Ln= Dy-Lu) and Ln 2 Hf 2 O 7 (Ln= Eu, Gd) …

LiYbSe2: Frustrated Magnetism in the Pyrochlore Lattice

RS Dissanayaka Mudiyanselage, H Wang… - Journal of the …, 2022 - ACS Publications
Three-dimensionally (3D) frustrated magnets generally exist in the magnetic diamond and
pyrochlore lattices, in which quantum fluctuations suppress magnetic orders and generate …

Liquidlike correlations in single-crystalline YMoO: An unconventional spin glass

HJ Silverstein, K Fritsch, F Flicker, AM Hallas… - Physical Review B, 2014 - APS
The spin-glass behavior of Y 2 Mo 2 O 7 has remained a puzzle for nearly three decades.
Free of bulk disorder within the resolution of powder diffraction methods, it is thought that this …

Role of defects in determining the magnetic ground state of ytterbium titanate

DF Bowman, E Cemal, T Lehner, AR Wildes… - Nature …, 2019 - nature.com
Pyrochlore systems are ideally suited to the exploration of geometrical frustration in three
dimensions, and their rich phenomenology encompasses topological order and fractional …

Effect of Long- and Short-Range Disorder on the Oxygen Ionic Conductivity of Tm2(Ti2–xTmx)O7–x/2 “Stuffed” Pyrochlores

BG Mullens, Z Zhang, M Avdeev, HEA Brand… - Inorganic …, 2021 - ACS Publications
The long-range average and short-range local structures in the Tm2 (Ti2–x Tm x) O7–x/2 (x=
0.00–0.67) series were studied using a combination of diffraction and spectroscopic …

Ion irradiation of novel yttrium/ytterbium-based pyrochlores: The effect of disorder

KR Whittle, MG Blackford, RD Aughterson, GR Lumpkin… - Acta Materialia, 2011 - Elsevier
Pyrochlores based on the general composition Ln2TiO5 (Ln2. 67Ti1. 33O6. 67) and
Ln2Ti2O7, where Ln= Y or Yb, have been irradiated through the crystalline–amorphous …

New physics in frustrated magnets: Spin ices, monopoles, etc.

AA Zvyagin - Low Temperature Physics, 2013 - pubs.aip.org
During recent years the interest to frustrated magnets has grown considerably. Such
systems reveal very peculiar properties which distinguish them from standard paramagnets …