Recent advances in polyoxometalate-based single-molecule magnets

ZX Yang, F Gong, D Lin, Y Huo - Coordination Chemistry Reviews, 2023 - Elsevier
Single-molecule magnets (SMMs) have attracted increasing attention in recent years due to
the potentially applicable in high-density information storage and spintronic devices. There …

Mitigating Raman relaxation for high-temperature single-molecule magnets

QC Luo, YZ Zheng - Trends in Chemistry, 2023 - cell.com
Previous studies on how to prolong the relaxation times of single-molecule magnets (SMMs)
focus on mitigating the quantum tunneling effect. However, recent progress shows that …

Magnetic hysteresis and large coercivity in bisbenzimidazole radical-bridged dilanthanide complexes

F Benner, L La Droitte, O Cador, B Le Guennic… - Chemical …, 2023 - pubs.rsc.org
A judicious combination of radical ligands innate to diffuse spin orbitals with paramagnetic
metal ions elicits strong magnetic exchange coupling which leads to properties important for …

Impact of 3d Metal Ions on the Magnetic Dynamics in Isostructural Tetranuclear Butterfly {Ni2IIDy2III} and {Co2IIDy2III} Complexes

NC Jana, A Escuer, R Herchel, J Serra… - Crystal Growth & …, 2024 - ACS Publications
This paper describes the synthesis, structures, and magnetic properties of four isostructural
butterfly-type heterometallic tetranuclear 3d-4f complexes,[Ni2Dy2 (HL1) 2 (μ3–OH) 2 (piv) …

Supermolecular Aggregates of Mononuclear and Asymmetric Dinuclear Dysprosium Single-Molecule Magnets Assembled by Intermolecular Hydrogen Bonds

Y Qin, CE Wu, CJ Li, ZT Cai, B Hu… - Crystal Growth & …, 2024 - ACS Publications
By manipulating the aggregate states of dysprosium single-molecule magnets (DyIII-SMMs),
the hydrogen bonds have played key roles in realizing aggregation-induced suppression of …

Insight into the Magnetic Exchange Interactions and Anisotropy in Heterobimetallic CuII–LnIII Complexes: A Rare Example of Cu–Gd Single-Molecule Magnets

NC Jana, Z Jagličić, R Herchel, P Brandão… - Crystal Growth & …, 2024 - ACS Publications
The exploration of heterometallic complexes containing both 3d and 4f metal ions has been
on the rise with advancements in the field of 3d–4f single-molecule magnets. The motivation …

Understanding electrostatics and covalency effects in highly anisotropic organometallic sandwich dysprosium complexes [Dy (C m R m) 2](where R= H, SiH 3, CH 3 …

I Tarannum, S Moorthy, SK Singh - Dalton Transactions, 2023 - pubs.rsc.org
In this article, we have thoroughly studied the electronic structure and 4f-ligand covalency of
six mononuclear dysprosium organometallic sandwich complexes [Dy (CmRm) 2] …

The effect of co-ligands on the performance of single-molecule magnet behaviours in a family of linear trinuclear Zn–Dy–Zn complexes with a compartmental Schiff …

R Nandy, Z Jagličić, NC Jana, P Brandão… - Dalton …, 2024 - pubs.rsc.org
We present herein magneto-structural studies of three heterometallic Zn2Dy
complexes:[Zn2Dy (L) 2Cl2 (H2O)](ClO4)· 4H2O (1),[Zn2Dy (L) 2Br2 (H2O)](ClO4)· 4H2O (2) …

Dynamic Magnetic Susceptibility Method in Studies of Coordination Compounds

NN Efimov, KA Babeshkin, AV Rotov - Russian Journal of Coordination …, 2024 - Springer
The measurement of the dynamic magnetic susceptibility is a universal method, which is
used for the evaluation of magnetic properties of single molecule magnets by scientists all …

Improving the performance of β-diketonate-based Dy III single-molecule magnets displaying luminescence thermometry

AG Bispo-Jr, L Yeh, D Errulat, DA Gálico… - Chemical …, 2023 - pubs.rsc.org
Herein, we present a luminescent single-molecule magnet,[Dy (acac) 3bpm](acac−=
acetylacetonate, bpm= 2, 2′-bipyrimidine), which displays luminescence thermometry with …