HFIP in organic synthesis

HF Motiwala, AM Armaly, JG Cacioppo… - Chemical …, 2022 - ACS Publications
1, 1, 1, 3, 3, 3-Hexafluoroisopropanol (HFIP) is a polar, strongly hydrogen bond-donating
solvent that has found numerous uses in organic synthesis due to its ability to stabilize ionic …

Recent applications of homogeneous catalysis in electrochemical organic synthesis

X Cheng, A Lei, TS Mei, HC Xu, K Xu… - CCS Chemistry, 2022 - chinesechemsoc.org
Although the combination of electrochemistry and homogeneous catalysis has proven to be
a powerful strategy for achieving a diverse array of novel transformations, some challenges …

Designing sites in heterogeneous catalysis: are we reaching selectivities competitive with those of homogeneous catalysts?

F Zaera - Chemical Reviews, 2022 - ACS Publications
A critical review of different prominent nanotechnologies adapted to catalysis is provided,
with focus on how they contribute to the improvement of selectivity in heterogeneous …

Electro-organic synthesis–a 21 st century technique

D Pollok, SR Waldvogel - Chemical science, 2020 - pubs.rsc.org
The severe limitations of fossil fuels and finite resources influence the scientific community to
reconsider chemical synthesis and establish sustainable techniques. Several promising …

Cross-dehydrogenative coupling: a sustainable reaction for C–C bond formations

T Tian, Z Li, CJ Li - Green Chemistry, 2021 - pubs.rsc.org
We are entering an era that emphasizes greenness and sustainability. Based on such a
philosophy, it is critical to uncover novel and original sustainable reaction modes for future …

A tutorial on asymmetric electrocatalysis

J Rein, SB Zacate, K Mao, S Lin - Chemical Society Reviews, 2023 - pubs.rsc.org
Electrochemistry has emerged as a powerful means to enable redox transformations in
modern chemical synthesis. This tutorial review delves into the unique advantages of …

Recent Advances in Oxidative R1-H/R2-H Cross-Coupling with Hydrogen Evolution via Photo-/Electrochemistry: Focus Review

H Wang, X Gao, Z Lv, T Abdelilah, A Lei - Chemical reviews, 2019 - ACS Publications
Photo-/electrochemical catalyzed oxidative R1-H/R2-H cross-coupling with hydrogen
evolution has become an increasingly important issue for molecular synthesis. The dream of …

Paired electrolysis-enabled nickel-catalyzed enantioselective reductive cross-coupling between α-chloroesters and aryl bromides

D Liu, ZR Liu, ZH Wang, C Ma, S Herbert… - Nature …, 2022 - nature.com
Electrochemical asymmetric catalysis has emerged as a sustainable and promising
approach to the production of chiral compounds and the utilization of both the anode and …

Synthetic organic electrochemical methods since 2000: on the verge of a renaissance

M Yan, Y Kawamata, PS Baran - Chemical Reviews, 2017 - ACS Publications
Electrochemistry represents one of the most intimate ways of interacting with molecules. This
review discusses advances in synthetic organic electrochemistry since 2000. Enabling …

Electrochemical strategies for C–H functionalization and C–N bond formation

MD Kärkäs - Chemical Society Reviews, 2018 - pubs.rsc.org
Conventional methods for carrying out carbon–hydrogen functionalization and carbon–
nitrogen bond formation are typically conducted at elevated temperatures, and rely on …