Selective air oxidation of light alkanes catalyzed by activated metalloporphyrins-the search for a suprabiotic system
PE Ellis Jr, JE Lyons - Coordination Chemistry Reviews, 1990 - Elsevier
Coordination Chemistry Reviews, 105 (1990) 181-193 alcohols Page 1 Coordination Chemistry
Reviews, 105 (1990) 181-193 Elsevier Science Publishers BV, Amsterdam 181 SELECTIVE …
Reviews, 105 (1990) 181-193 Elsevier Science Publishers BV, Amsterdam 181 SELECTIVE …
The synthesis of meso-substituted porphyrins
JS Lindsey - Metalloporphyrins Catalyzed Oxidations, 1994 - Springer
The synthesis of meso-substituted porphyrins has traditionally been achieved under rather
forcing conditions (Figure 1). In the Rothemund method (ca. 1941) an aldehyde and pyrrole …
forcing conditions (Figure 1). In the Rothemund method (ca. 1941) an aldehyde and pyrrole …
Iron(II)‐Catalyzed Site‐Selective Functionalization of Unactivated C(sp3)−H Bonds Guided by Alkoxyl Radicals
H Guan, S Sun, Y Mao, L Chen, R Lu… - Angewandte …, 2018 - Wiley Online Library
An alkoxyl radical guided strategy for site‐selective functionalization of unactivated
methylene and methine C− H bonds enabled by an FeII‐catalyzed redox process is …
methylene and methine C− H bonds enabled by an FeII‐catalyzed redox process is …
Remarkably stable iron porphyrins bearing nonheteroatom-stabilized carbene or (alkoxycarbonyl) carbenes: Isolation, X-ray crystal structures, and carbon atom …
Y Li, JS Huang, ZY Zhou, CM Che… - Journal of the American …, 2002 - ACS Publications
Reactions of [Fe (TPFPP)](TPFPP= meso-tetrakis (pentafluorophenyl) porphyrinato dianion)
with diazo compounds N2C (Ph) R (R= Ph, CO2Et, CO2CH2CH CH2) afforded [Fe …
with diazo compounds N2C (Ph) R (R= Ph, CO2Et, CO2CH2CH CH2) afforded [Fe …
Steric and electronic control of iron porphyrin catalyzed hydrocarbon oxidations
MJ Nappa, CA Tolman - Inorganic Chemistry, 1985 - ACS Publications
The yields and product distributions in the oxidation of hydrocarbons (cyclohexane, n-
pentane, n-octane, methylcyclohexane, terf-butylcyclohexane, and ethylbenzene), using …
pentane, n-octane, methylcyclohexane, terf-butylcyclohexane, and ethylbenzene), using …
Proton-coupled O− O activation on a redox platform bearing a hydrogen-bonding scaffold
CJ Chang, LL Chng, DG Nocera - Journal of the American …, 2003 - ACS Publications
Porphyrin architectures bearing a hydrogen-bonding scaffold have been synthesized. The H-
bond pendant allows proton-coupled electron transfer (PCET) to be utilized as a vehicle for …
bond pendant allows proton-coupled electron transfer (PCET) to be utilized as a vehicle for …
Oxygenation patterns for iron (II) porphyrins. Peroxo and ferryl (FeIVO) intermediates detected by proton nuclear magnetic resonance spectroscopy during the …
AL Balch, YW Chan, RJ Cheng… - Journal of the …, 1984 - ACS Publications
The reaction between unligated (tetramesitylporphyrin) iron (II)(TMPFe11) and dioxygen in a
toluene solution has been examined by NMR spectroscopy. At-70 C, TMPFe11 reacts with …
toluene solution has been examined by NMR spectroscopy. At-70 C, TMPFe11 reacts with …
meso-Tetraphenylporphyrin Iron Chloride Catalyzed Selective Oxidative Cross-Coupling of Phenols
H Shalit, A Libman, D Pappo - Journal of the American Chemical …, 2017 - ACS Publications
A novel catalytic system for oxidative cross-coupling of readily oxidized phenols with poor
nucleophilic phenolic partners based on an iron meso-tetraphenylporphyrin chloride (Fe …
nucleophilic phenolic partners based on an iron meso-tetraphenylporphyrin chloride (Fe …
“Hangman” porphyrins for the assembly of a model heme water channel
CY Yeh, CJ Chang, DG Nocera - Journal of the American …, 2001 - ACS Publications
The heme unit is one of the most ubiquitous and versatile cofactors found in Nature. 1, 2 The
amazingly diverse reactivities displayed by heme-dependent enzymes (eg, O2 transport and …
amazingly diverse reactivities displayed by heme-dependent enzymes (eg, O2 transport and …
Influence of hydrogen ion activity and general acid-base catalysis on the rate of decomposition of hydrogen peroxide by a novel nonaggregating water-soluble iron (III) …
MF Zipplies, WA Lee, TC Bruice - Journal of the American …, 1986 - ACS Publications
The synthesis and characterization of 5, 10, 15, 20-tetrakis (2, 6-dimethyl-3-sulfonatophenyl)
porphyrin (3) and its iron (III) complex (3-Fem) are described. Both 3 and 3-Fem hydrate …
porphyrin (3) and its iron (III) complex (3-Fem) are described. Both 3 and 3-Fem hydrate …