Methods to functionalize arenes and heteroarenes in a site-selective manner are highly
sought after for rapidly constructing value-added molecules of medicinal, agrochemical, and …

Atropisomers are stereoisomers with axial chirality arising from restricted rotation around a
single bond. Lots of representatives of this class of axially chiral compounds exhibit …

The Marchantiophyta (liverworts) are rich sources of phenolic substances, especially cyclic
and acyclic bis-bibenzyls, which are rare natural products in the plant kingdom, together with …

Iron Halide-Mediated Regio- and Stereoselective Halosulfonylation of Terminal Alkynes with
Sulfonylhydrazides: Synthesis of (E)-β-Chloro and Bromo Vinylsulfones | The Journal of Organic …

Over the past several decades, macrocyclic compounds have emerged as increasingly
significant therapeutic candidates in drug discovery. Their pharmacological activity hinges …

Abstract The Bestmann–Ohira reagent is a unique and versatile reagent in organic
synthesis. It is a well‐known homologating agent for the conversion of aldehydes into the …

Despite the proven value in utilizing pyrone dienes to create molecular complexity via Diels–
Alder reactions with varied dienophiles, few examples of effective catalytic, asymmetric …

Diels‐Alder reaction is one of the most important reactions in organic synthesis and has
witnessed great achievements in total syntheses of complex natural products. In this review …

Ethylene bridged azobenzenes are novel, promising molecular switches that are
thermodynamically more stable in the (Z) than in the (E) configuration, contrary to the linear …

Abstract The total synthesis of (+)‐cavicularin is described. The synthesis features an
enantio‐and regioselective pyrone Diels–Alder reaction of a vinyl sulfone to construct the …