The transition metal-catalysed hydroboration reaction
The use of transition metals to catalyse the addition of hydridoboranes to unsaturated
organic molecules was initially realised several decades ago. Although this area of …
organic molecules was initially realised several decades ago. Although this area of …
Molecular main group metal hydrides
This review serves to document advances in the synthesis, versatile bonding, and reactivity
of molecular main group metal hydrides within Groups 1, 2, and 12–16. Particular attention …
of molecular main group metal hydrides within Groups 1, 2, and 12–16. Particular attention …
Organic synthesis with the most abundant transition metal–iron: from rust to multitasking catalysts
In industries and academic laboratories, several late transition metal-catalyzed prerequisite
reactions are widely performed during single and multistep synthesis. However, besides the …
reactions are widely performed during single and multistep synthesis. However, besides the …
Catalytic hydroboration of carbonyl derivatives, imines, and carbon dioxide
Organoborane compounds present a class of versatile synthetic intermediate for myriad
organic transformations. The direct addition of a B–H bond across unsaturated bond …
organic transformations. The direct addition of a B–H bond across unsaturated bond …
Recent advances in the catalytic hydroboration of carbonyl compounds
ML Shegavi, SK Bose - Catalysis Science & Technology, 2019 - pubs.rsc.org
The chemoselective catalytic hydroboration of aldehydes and ketones has found
widespread applications in organic chemistry due to the synthetic utility of borate ester …
widespread applications in organic chemistry due to the synthetic utility of borate ester …
Pushing Chemical Boundaries with N-Heterocyclic Olefins (NHOs): From Catalysis to Main Group Element Chemistry
Conspectus N-Heterocyclic olefins (NHOs) have gone from the topic of a few scattered (but
important) reports in the early 1990s to very recently being a ligand/reagent of choice in the …
important) reports in the early 1990s to very recently being a ligand/reagent of choice in the …
Highly Selective Hydroboration of Alkenes, Ketones and Aldehydes Catalyzed by a Well‐Defined Manganese Complex
Well‐defined manganese complexes based on inexpensive, readily available ligands, 2,
2′: 6′, 2′′‐terpyridine and its derivatives have been prepared and employed for the …
2′: 6′, 2′′‐terpyridine and its derivatives have been prepared and employed for the …
Alkali Metal Hydridotriphenylborates [(L)M][HBPh3] (M = Li, Na, K): Chemoselective Catalysts for Carbonyl and CO2 Hydroboration
D Mukherjee, H Osseili, TP Spaniol… - Journal of the American …, 2016 - ACS Publications
Light alkali metal hydridotriphenylborates M [HBPh3](M= Li, Na, K), characterized as tris {2-
(dimethylamino) ethyl} amine (L) complexes [(L) M][HBPh3], act as efficient catalysts for the …
(dimethylamino) ethyl} amine (L) complexes [(L) M][HBPh3], act as efficient catalysts for the …
Aluminum monohydride catalyzed selective hydroboration of carbonyl compounds
The well-defined aluminum monohydride compound [{(2, 4, 6-Me3-C6H2) NC (Me)} 2
(Me)(H)] AlH·(NMe2Et)(1) catalyzes hydroboration of a wide range of aldehydes and …
(Me)(H)] AlH·(NMe2Et)(1) catalyzes hydroboration of a wide range of aldehydes and …
Metal‐Free σ‐Bond Metathesis in 1, 3, 2‐Diazaphospholene‐Catalyzed Hydroboration of Carbonyl Compounds
The first metal‐free catalytic hydroboration of carbonyl derivatives has been developed in
which a catalytic amount of 1, 3, 2‐diazaphospholene effectively promotes a hydroboration …
which a catalytic amount of 1, 3, 2‐diazaphospholene effectively promotes a hydroboration …