N, N-Dimethylformamide: much more than a solvent

J Muzart - Tetrahedron, 2009 - Elsevier
N, N-Dimethylformamide (DMF) is an excellent polar solvent for various classes of
compounds, the dissolution being favoured by interactions of the substrate with DMF. In the …

Copper-catalyzed oxidative carbon–heteroatom bond formation: a recent update

X Zhu, S Chiba - Chemical Society Reviews, 2016 - pubs.rsc.org
Copper-catalyzed oxidative carbon–heteroatom bond formation: a recent update - Chemical
Society Reviews (RSC Publishing) DOI:10.1039/C5CS00882D Royal Society of Chemistry …

Synthesis of Isoquinolines from α‐Aryl Vinyl Azides and Internal Alkynes by Rh–Cu Bimetallic Cooperation

YF Wang, KK Toh, JY Lee, S Chiba - Angewandte Chemie, 2011 - infona.pl
Katalysatoren als Partner: Im Schema ist ein neues Verfahren zur Synthese hoch
substituierter Isochinoline illustriert (Cp*= C 5 Me 5, DMF= N, N‐Dimethylformamid …

Potential Safety Hazards Associated with Using N,N-Dimethylformamide in Chemical Reactions

Q Yang, M Sheng, Y Huang - Organic Process Research & …, 2020 - ACS Publications
N, N-Dimethylformamide (DMF) is frequently used as a solvent because of its unique
physical properties that allow it to solubilize both organic and inorganic substances. It has …

Synthesis of Azaheterocycles from Aryl Ketone O-Acetyl Oximes and Internal Alkynes by Cu–Rh Bimetallic Relay Catalysts

PC Too, SH Chua, SH Wong… - The Journal of Organic …, 2011 - ACS Publications
A synthetic method for azaheterocycles from aryl ketone O-acetyl oximes and internal
alkynes has been developed by using the Cu (OAc) 2–[Cp* RhCl2] 2 bimetallic catalytic …

Application of organic azides for the synthesis of nitrogen-containing molecules

S Chiba - Synlett, 2012 - thieme-connect.com
Thieme E-Journals - Synlett / Full Text DE EN Home Products Journals Books Book Series
Service Library Service Help Contact Portal SYNLETT Full-text search Full-text search Author …

Anti‐Markovnikov Hydrofunctionalization of Alkenes: Use of a Benzyl Group as a Traceless Redox‐Active Hydrogen Donor

GH Lonca, DY Ong, TMH Tran, C Tejo… - Angewandte Chemie …, 2017 - Wiley Online Library
A protocol for the anti‐Markovnikov hydrofunctionalization of alkenes has been developed
by the use of a benzyl group as a traceless redox‐active hydrogen donor. Under copper …

Synthesis of N-Alkyl Substituted Benzimidazoquinazolinones

GG Dake, N Blanchard, KP Kaliappan - ACS omega, 2024 - ACS Publications
Aromatic N-heterocycles, especially benzimidazoquinazolinones featuring alkyl chains, hold
significant pharmaceutical relevance. Here, we introduce a streamlined one-pot, 2-fold Cu …

DMF as a Source of Oxygen and Aminomethine: Stereoselective 1, 2-Insertion of Rhodium (II) Azavinyl Carbenes into the C O Bond of Formamides for the Synthesis …

DJ Jung, HJ Jeon, JH Kim, Y Kim, S Lee - Organic letters, 2014 - ACS Publications
A new catalytic reaction in which all the atoms of a formamide are incorporated into the
product through a formal stereoselective 1, 2-insertion of rhodium (II) azavinyl carbenes …

Pd-catalyzed reduction of aryl halides using dimethylformamide as the hydride source

AM Zawisza, J Muzart - Tetrahedron Letters, 2007 - Elsevier
The Pd-catalyzed homocoupling of aryl halides in a basic DMF solution is often
accompanied by the dehalogenation of the substrate as side reaction. When an inorganic …