The less-expensive and earth-abundant nickel catalyst is highly promising in the
copolymerization of ethylene with polar monomers and has thus attracted increasing …

Polyolefins play a crucial role in the polymer industry because of their low-cost monomers
and well-established production processes. Recent years have witnessed tremendous …

Transition‐metal‐catalyzed copolymerization of ethylene with carbon monoxide affords
polyketones materials with excellent mechanical strength, photodegradability, surface and …

Transition metal‐catalyzed copolymerization of CO and ethylene has a strong inherent
propensity to produce the strictly alternating copolymer. In this work, nickel catalysts capable …

This paper initially reports the remote binding of B (C6F5) 3 to zwitterionic nickel and
palladium allyl complexes bearing an α-sulfonate-β-diimine ligand and the ion pair effects of …

A Ni catalyst has been developed that is highly productive for the alternating CO-ethylene
copolymer and capable of incorporating a substantial amount of propylene to produce the …

The carbonylative polymerization of olefin yields aliphatic polyketones, which are used as
engineering plastics in the market due to their excellent mechanical strength, chemical …

The copolymerization of olefins with carbon monoxide (CO) affords aliphatic polyketones,
which exhibit excellent mechanical strength, crystallinity, photodegradability, hydrophilicity …

Commercial polyketone materials are generally produced by palladium-catalyzed
terpolymerization of ethylene and α-olefin with carbon monoxide (CO), and rare examples …

Enhanced rates and selectivity in enzymes are enabled in part by precisely tuned electric
fields within active sites. Analogously, the use of charged groups to leverage electrostatics in …