Even though the existence of 1, 2, 3‐triazoles has been known for more than a century, the
recent discovery of a copper (I) catalyzed version of this reaction has attributed …

A continuous shape measures analysis of the coordination polyhedra of a host of transition
metal complexes with bi-and multidentate ligands discloses the distortion pathway …

Biological encapsulants, such as viral capsids and ferritin protein cages, use many identical
subunits to tile the surface of a polyhedron. Inspired by these natural systems, synthetic …

Coordination-driven self-assembly enables the spontaneous construction of metallo-
supramolecules with high precision, facilitated by dynamic and reversible metal–ligand …

During the past two decades, density-functional (DF) theory has evolved from niche
applications for simple solid-state materials to become a workhorse method for studying a …

The azido ligand is one of the most investigated ligands in magnetochemistry. Despite its
importance, not much is known about the ligand field of the azido ligand and its influence on …

In biological systems, many biomacromolecules (eg, heme proteins) are capable of
switching their states reversibly in response to external stimuli, endowing these natural …

Two closely related FeII complexes with 2, 6-bis (1-ethyl-1H-1, 2, 3-triazol-4yl) pyridine and
2, 6-bis (1, 2, 3-triazol-5-ylidene) pyridine ligands are presented to gain new insights into the …

Abstract The complex [FeL2][BF4] 2 (1; L= 4‐(isopropylsulfanyl)‐2, 6‐di (pyrazol‐1‐yl)
pyridine) forms solvate crystals 1⋅ solv (solv= MeNO2, MeCN, EtCN, or Me2CO). Most of …

In this review, we analyze the stereochemistry of hexacoordinated metal complexes with
flexible tridentate ligands. Unlike rigid ligands, which can adopt only specific coordination …