Single-atom alloy catalysis

RT Hannagan, G Giannakakis… - Chemical …, 2020 - ACS Publications
Single-atom alloys (SAAs) play an increasingly significant role in the field of single-site
catalysis and are typically composed of catalytically active elements atomically dispersed in …

Designing artificial metalloenzymes by tuning of the environment beyond the primary coordination sphere

C Van Stappen, Y Deng, Y Liu, H Heidari… - Chemical …, 2022 - ACS Publications
Metalloenzymes catalyze a variety of reactions using a limited number of natural amino
acids and metallocofactors. Therefore, the environment beyond the primary coordination …

Cu-mediated Ullmann-type cross-coupling and industrial applications in route design, process development, and scale-up of pharmaceutical and agrochemical …

Q Yang, Y Zhao, D Ma - Organic Process Research & …, 2022 - ACS Publications
Cu-mediated Ullmann-type cross-coupling has experienced significant advances over the
last century since the seminal publication by Ullmann in 1901. These advances have …

The Buchwald–Hartwig amination after 25 years

R Dorel, CP Grugel, AM Haydl - … Chemie International Edition, 2019 - Wiley Online Library
The Pd‐catalyzed coupling of aryl (pseudo) halides and amines is one of the most powerful
approaches for the formation of C (sp2)− N bonds. The pioneering reports from Migita and …

Visible‐light photocatalysis: does it make a difference in organic synthesis?

L Marzo, SK Pagire, O Reiser… - Angewandte Chemie …, 2018 - Wiley Online Library
Visible‐light photocatalysis has evolved over the last decade into a widely used method in
organic synthesis. Photocatalytic variants have been reported for many important …

High electric field on water microdroplets catalyzes spontaneous and ultrafast oxidative C–H/N–H cross-coupling

D Zhang, X Yuan, C Gong, X Zhang - Journal of the American …, 2022 - ACS Publications
Oxidative C–H/N–H cross-coupling has emerged as an atom-economical method for the
construction of C–N bonds. Conventional oxidative C–H/N–H coupling requires at least one …

Selected Copper‐Based Reactions for C− N, C− O, C− S, and C− C Bond Formation

S Bhunia, GG Pawar, SV Kumar… - Angewandte Chemie …, 2017 - Wiley Online Library
Metal‐catalyzed cross‐coupling reactions belong to the most important transformations in
organic synthesis. Copper catalysis has received great attention owing to the low toxicity …

Cyclic (alkyl)-and (aryl)-(amino) carbene coinage metal complexes and their applications

R Jazzar, M Soleilhavoup, G Bertrand - Chemical reviews, 2020 - ACS Publications
Cyclic (alkyl)-and (aryl)-(amino) carbenes (CAACs and CAArCs) are stronger σ-donors and
π-acceptors than imidazol-2-ylidenes and imidazolidin-2-ylidenes, the well-known N …

Biosynthesis of CuO nanoparticles using aqueous extract of herbal tea (Stachys Lavandulifolia) flowers and evaluation of its catalytic activity

H Veisi, B Karmakar, T Tamoradi, S Hemmati… - Scientific Reports, 2021 - nature.com
Plant derived biogenic synthesis of nanoparticles (NP) has been the recent trend in material
science as featured sustainable catalysts. A great deal of the current nanocatalytic research …

A pharmaceutical industry perspective on sustainable metal catalysis

JD Hayler, DK Leahy, EM Simmons - Organometallics, 2018 - ACS Publications
As companies grow ever more mindful of the sustainability aspects of their products and
supply chains, an increasing focus on the environmental impact of pharmaceutical …