[HTML][HTML] Hydrogenase-based oxidative biocatalysis without oxygen

A Al-Shameri, DL Siebert, S Sutiono… - Nature …, 2023 - nature.com
Biocatalysis-based synthesis can provide a sustainable and clean platform for producing
chemicals. Many oxidative biocatalytic routes require the cofactor NAD+ as an electron …

[HTML][HTML] Strategies for the synthesis of the osmolyte glucosylglycerate and its precursor glycerate

Y Allaert, A Leyder, J Franceus, T Desmet - Applied Microbiology and …, 2024 - Springer
Glycosidic osmolytes are widespread natural compounds that protect microorganisms and
their macromolecules from the deleterious effects of various environmental stresses. Their …

Current Advances in the Enzyme Engineering of O2‐Dependent Enzymes – Boosting the Versatility and Applicability of Oxygenases and Oxidases

A Al‐Shameri, L Schmermund, V Sieber - ChemCatChem, 2024 - Wiley Online Library
Oxidation reactions catalysed by O2‐dependent enzymes are gaining increasing interest in
the chemical industry due to their potential to provide a more selective and sustainable …

[HTML][HTML] Directed evolution of Rhodotorula gracilis d-amino acid oxidase using single-cell hydrogel encapsulation and ultrahigh-throughput screening

C Küng, R Vanella, MA Nash - Reaction Chemistry & Engineering, 2023 - pubs.rsc.org
Engineering catalytic and biophysical properties of enzymes is an essential step en route to
advanced biomedical and industrial applications. Here, we developed a high-throughput …

Metal Affinity Fusion Enzyme Immobilization: Batch Process Showcase for Cascading Alcohol Oxidation and Bayer–Villiger Oxidation in Microaqueous Media

G Vernet, Y Ma, S Serban, A Basso… - ACS Sustainable …, 2024 - ACS Publications
Baeyer–Villiger monooxygenases (BVMOs) show great potential for the selective oxidation
of a wide scope of ketones with exceptional regio-, chemo-, or stereoselectivity to produce …

Overcoming Biochemical Limitations of Galactose Oxidase through the Design of a Solid‐Supported Self‐Sufficient Biocatalyst

A Lorente‐Arevalo, G Orellana, M Ladero… - …, 2023 - Wiley Online Library
Abstract Galactose Oxidase (GalOx) has gained significant interest in biocatalysis due to its
ability for selective oxidation beyond the natural oxidation of galactose, enabling the …

[HTML][HTML] Mirror, mirror on the wall, which is the greenest of them all? A critical comparison of chemo-and biocatalytic oxyfunctionalisation reactions

Y Wu, CE Paul, F Hollmann - Green Carbon, 2023 - Elsevier
This review article critically compares two widely used types of catalysis, chemo-and
biocatalysis, and provides insights on their greenness according to specified parameters. A …

[HTML][HTML] Intensification of a biocatalytic oxidation under fine bubble aeration in a rotating bed reactor

Z Perçin, L Kursula, E Löfgren, E Byström… - Biochemical …, 2024 - Elsevier
The utilization of oxidases suffers from insufficient oxygen availability due to its low solubility
in gas-liquid multiphase systems. To overcome this limitation, oxygen is continuously …