Ligand substitution reactions at inorganic centers

DT Richens - Chemical reviews, 2005 - ACS Publications
Ligand or group substitution (exchange) comprises one of the most fundamental processes
occurring at an inorganic center in the solution phase. 1, 2 Extensive reviews of this topic …

Off the Beaten Track—A Hitchhiker's Guide to Beryllium Chemistry

D Naglav, MR Buchner, G Bendt… - Angewandte Chemie …, 2016 - Wiley Online Library
This Minireview aims to give an introduction to beryllium chemistry for all less‐experienced
scientists in this field of research. Up to date information on the toxicity of beryllium and its …

Synthesis and structure of an ionic beryllium-“carbene” complex

WA Herrmann, O Runte, G Artus - Journal of organometallic chemistry, 1995 - Elsevier
The Lewis-acidic metal ion Be2+ forms stable adducts with the carbene 1, 3-
dimethylimidazolin-2-ylidene (L). The pronounced nucleophilicity of the ligand is …

Schlenk‐Type Equilibria of Grignard‐Analogous Arylberyllium Complexes: Steric Effects

C Helling, C Jones - Chemistry–A European Journal, 2023 - Wiley Online Library
The presence of complex Schlenk equilibria is a central property of synthetically invaluable
Grignard reagents substantially affecting their reactivity and selectivity in chemical …

Advances in beryllium coordination chemistry

LC Perera, O Raymond, W Henderson… - Coordination Chemistry …, 2017 - Elsevier
Beryllium has a unique combination of properties which has made it a vital component in a
wide range of technical sectors and consumer industries. However, beryllium is extremely …

Recent contributions to the coordination chemistry of beryllium

MR Buchner - Chemistry–A European Journal, 2019 - Wiley Online Library
Given the alleged extreme toxicity of beryllium and its compounds, it is the least investigated
nonradioactive element. However, beryllium exhibits unique properties among the elements …

Di-ortho-beryllated Carbodiphosphorane: A Compound with a Metal–Carbon Double Bond to an Element of the s-Block

MR Buchner, S Pan, C Poggel, N Spang… - …, 2020 - ACS Publications
Double bonds have been realized for a wide variety of elements in the p-, d-, and f-blocks.
However, no s-block metal complexes with a double bond have been identified. Here we …

Recent trends in metal alkoxide chemistry

RC Mehrotra, A Singh - Progress in inorganic chemistry, 1997 - Wiley Online Library
Recent trends in metal alkoxide chemistry Page 244 Recent Trends in Metal Alkoxide Chemistry
RAM C. MEHROTRA and ANIRUDH SINGH Department of Chemistry University of Rajasthan …

Synthesis, 9Be NMR Spectroscopy, and Structural Characterization of Sterically Encumbered Beryllium Compounds

M Niemeyer, PP Power - Inorganic chemistry, 1997 - ACS Publications
The use of the terphenyl substituent− C6H3-2, 6-Mes2 (abbreviated Ar) has permitted the
synthesis of several new low-coordinate beryllium compounds. Reaction of 1 equiv of LiAr …

Synthesis, Structural Characterization, and bonding of molecular heavier beryllium chalcogenides

C Czernetzki, T Tröster, L Endres… - … A European Journal, 2023 - Wiley Online Library
The reactions of a cyclic alkyl (amino) carbene (CAAC)‐stabilized beryllium radical with
E2Ph2 (E= S, Se, Te) and of a beryllole with HEPh (E= S, Se) yield the corresponding …