Asymmetric catalysis with chiral metal complexes has received considerable attention in
recent years, and its contribution to the art of organic synthesis has become of leading …

This review covers literature on non-stabilized functionalized organolithium compounds
since 1997. In this overview, we consider intermediates with different separation between …

A cumene solution of α-stannyl benzyl phenyl sulfide was treated with n-BuLi and bis
(oxazoline)-i Pr at− 78° C and subsequently with benzophenone to give the product with …

An enantioselective nucleophilic substitution reaction of achiral dialkoxysilane has been
developed. The reaction proceeds with efficient stereocontrol on the silicon chirality center to …

A variety of prop-2-ynylamides have been carbonylated under oxidative conditions to give
oxazolines, oxazolines with chelating groups, and bisoxazolines bearing an …

An investigation into the use of phase-transfer catalysis for the [2, 3]-sigmatropic
rearrangement of allyloxy carbonyl compounds is described. Initial studies focused on …

The hydroamination of vinylarenes with primary and secondary amines was studied with
catalytic amounts as low as 2 mol‐% of LiN (SiMe3) 2/TMEDA. Reactions proceeded readily …

While the use of stoichiometric amounts of sparteine and related ligands in various
asymmetric reactions often lead to highly enantioselective transformations, there have been …

Planar Chiral Cyclic Ether: Asymmetric Resolution and Chirality Transformation | Journal of
the American Chemical Society ACS ACS Publications C&EN CAS Find my institution Log In …

Enantioselective α-deprotonation–rearrangement of achiral substituted cyclooctene oxides
7, 27 and 28 and N-Boc hexahydroazonine oxide 45 using organolithiums in the presence …