Palladium/norbornene cooperative catalysis has emerged as a distinct approach to
construct polyfunctionalized arenes from readily available starting materials. This Review …

Conspectus Benzo-fused skeletons are ubiquitous in agrochemicals, medicines, natural
products, catalysts, and other organic function materials. The assembly of these skeletons in …

An unprecedented Pd‐catalyzed fluorinative bifunctionalization of aziridines and azetidines
was successfully developed via regioselective C− C and C− F bond cleavage of gem …

The Catellani reaction is known as a powerful strategy for the expeditious synthesis of highly
substituted arenes and benzo‐fused rings, which are usually difficult to access through …

In this work, we describe a Catellani-type C–H glycosylation to provide rapid access to
various highly decorated α-C-(hetero) aryl glycosides in a modular and stereoselective …

Palladium/norbornene (Pd/NBE) cooperative catalysis has received enormous attention and
found numerous synthetic applications in the past two decades. Considering the critical …

The Catellani reaction is a palladium-catalyzed hydrocarbon-activated multicomponent
tandem reaction involving an aryl halide, an electrophilic coupling reagent and a terminating …

Transition-metal-catalyzed alkylation of (hetero) arenes with three-membered carbo-
/heterocycles involving C–H activation and ring scission has been greatly developed over …

We report a dual-tasked methylation that is based on cooperative palladium/norbornene
catalysis. Readily available (hetero) aryl halides (39 iodides and 4 bromides) and …

Sequential, domino and tandem reactions could be defined as a sequence of synthetic
transformations that occur one after the other, in the same reaction flask. This Review …