Though often perceived as the simple metaphorical hybrid of synthetic inorganic and
organic chemistry, synthetic organometallic chemistry continues to vigorously differentiate …

Olefins and alkynes are ubiquitous in transition‐metal catalysis, whether introduced by the
substrate, the catalyst, or as an additive. Whereas the impact of metals and ligands is …

The combinative and complementary use of a hemilabile difunctional ligand on a metal,
notably palladium, that is coordinatively and electronically unsaturated has led to the …

Palladium-catalyzed Negishi cross-coupling involving primary and secondary alkyls, even in
the presence of β-H, can be achieved at ambient temperature using chelating ligands …

A new class of easily accessible hemilabile benzimidazolyl phosphine ligands has been
developed. The ligand skeleton is prepared from commercially available and inexpensive o …

Two new pincer type Pd (II)-Schiff base complexes of the general formula [PdL 1 (PPh 3)] 1
and [PdL 2 (PPh 3)] 2,(where L 1= 2-(2, 3-Dihydroxybenzylideneamino) phenolate and L 2 …

In recent years, Pd-catalyzed cross-coupling reactions have been used widely as
expeditious reactions in various fields of chemistry. Traditionally, these cross-coupling …

The reactivity of palladium (0) complexes,[Pd02 (dba‐n, n′‐Z) 3](n, n′‐Z= 4, 4′‐F; 4, 4′‐
CF3; 4, 4′‐H; 4, 4′‐MeO) and [Pd0 (dba‐n, n′‐Z) 2](n, n′‐Z= 4, 4′‐CF3; 4, 4′‐H; 3 …

Results from a mechanistic study on the Ni (COD) 2− bipy-catalyzed alkylation of anhydrides
are consistent with turnover-limiting reductive elimination at high Et2Zn concentrations …

Palladium (II) 3-iminophosphine derivatives were screened as intermolecular
hydroamination catalysts, with (3-iminophosphine)(allyl) palladium triflate determined to be …