The chemistry of porous organic molecular materials

MA Little, AI Cooper - Advanced Functional Materials, 2020 - Wiley Online Library
Porous organic molecular materials are a subclass of porous solids that are defined by their
modular, molecular structures, and the absence of extended covalent or coordination …

Supramolecular assemblies on surfaces: nanopatterning, functionality, and reactivity

DP Goronzy, M Ebrahimi, F Rosei, Arramel, Y Fang… - ACS …, 2018 - ACS Publications
Understanding how molecules interact to form large-scale hierarchical structures on
surfaces holds promise for building designer nanoscale constructs with defined chemical …

Molecular self‐assembly on graphene

JM MacLeod, F Rosei - Small, 2014 - Wiley Online Library
The formation of ordered arrays of molecules via self‐assembly is a rapid, scalable route
towards the realization of nanoscale architectures with tailored properties. In recent years …

Carboxylic acids: versatile building blocks and mediators for two-dimensional supramolecular self-assembly

M Lackinger, WM Heckl - Langmuir, 2009 - ACS Publications
Two-dimensional (2D) supramolecular self-assembly of various organic molecules at the
liquid− solid interface is presented and discussed with a focus on compounds that are …

Concentration-dependent supramolecular engineering of hydrogen-bonded nanostructures at surfaces: predicting self-assembly in 2D

A Ciesielski, PJ Szabelski, W Rzysko… - Journal of the …, 2013 - ACS Publications
We report a joint computational and experimental study on the concentration-dependent self-
assembly of a flat C 3-symmetric molecule at surfaces. As a model system we have chosen a …

Mastering fundamentals of supramolecular design with carboxylic acids. Common lessons from X-ray crystallography and scanning tunneling microscopy

O Ivasenko, DF Perepichka - Chemical Society Reviews, 2011 - pubs.rsc.org
Hydrogen bonding is one of the most important non-covalent interactions in both biological
(DNA, peptides, saccharides etc.) and artificial systems (various soft materials, host–guest …

Mining predicted crystal structure landscapes with high throughput crystallisation: old molecules, new insights

P Cui, DP McMahon, PR Spackman, BM Alston… - Chemical …, 2019 - pubs.rsc.org
Organic molecules tend to close pack to form dense structures when they are crystallised
from organic solvents. Porous molecular crystals defy this rule: they contain open space …

Halogen bonds in 2D supramolecular self-assembly of organic semiconductors

R Gutzler, C Fu, A Dadvand, Y Hua, JM MacLeod… - Nanoscale, 2012 - pubs.rsc.org
Weak interactions between bromine, sulphur, and hydrogen are shown to stabilize 2D
supramolecular monolayers at the liquid–solid interface. Three different thiophene-based …

Kinetics and thermodynamics in surface-confined molecular self-assembly

R Gutzler, L Cardenas, F Rosei - Chemical Science, 2011 - pubs.rsc.org
Two-dimensional molecular self-assembly at the liquid/solid interface is a widely employed
approach in surface science to pattern surfaces at the nanometre scale. A multitude of …

Programmable hierarchical three-component 2D assembly at a liquid− solid interface: recognition, selection, and transformation

S Lei, M Surin, K Tahara, J Adisoejoso, R Lazzaroni… - Nano …, 2008 - ACS Publications
Recognition and selection are of fundamental importance for the hierarchical assembly of
supramolecular systems. Coronene induces the formation of a hydrogen-bonded isophthalic …