Synthetic molecular motors and mechanical machines

ER Kay, DA Leigh, F Zerbetto - … Chemie International Edition, 2007 - Wiley Online Library
The widespread use of controlled molecular‐level motion in key natural processes suggests
that great rewards could come from bridging the gap between the present generation of …

Heterocycle-appended porphyrins: synthesis and challenges

IA Abdulaeva, KP Birin… - Coordination Chemistry …, 2020 - Elsevier
Porphyrin and their versatile metal complexes represent a special class of coordination
compounds possessing unique physical-chemical properties. The achievements in the …

Photoinduced Intramolecular Charge Transfer and S2 Fluorescence in Thiophene‐π‐Conjugated Donor–Acceptor Systems: Experimental and TDDFT Studies

GJ Zhao, RK Chen, MT Sun, JY Liu… - … A European Journal, 2008 - Wiley Online Library
Experimental and theoretical methods were used to study newly synthesized thiophene‐π‐
conjugated donor–acceptor compounds, which were found to exhibit efficient intramolecular …

Charge shift and triplet state formation in the 9-mesityl-10-methylacridinium cation

AC Benniston, A Harriman, P Li… - Journal of the …, 2005 - ACS Publications
The target donor− acceptor compound forms an acridinium-like, locally excited (LE) singlet
state on illumination with blue or near-UV light. This LE state undergoes rapid charge …

Intervalence (charge-resonance) transitions in organic mixed-valence systems. Through-space versus through-bond electron transfer between bridged aromatic …

DL Sun, SV Rosokha, SV Lindeman… - Journal of the American …, 2003 - ACS Publications
Intervalence absorption bands appearing in the diagnostic near-IR region are consistently
observed in the electronic spectra of mixed-valence systems containing a pair of aromatic …

[HTML][HTML] Antimony porphyrin complexes as visible-light driven photocatalyst

T Shiragami, J Matsumoto, H Inoue… - Journal of Photochemistry …, 2005 - Elsevier
This paper reviews the physicochemical properties and the photocatalytic application of
antimony porphyrin complexes (SbTPP). A variety of antimony porphyrin complexes have …

Modulating Charge‐Transfer Interactions in Topologically Different Porphyrin–C60 Dyads

DM Guldi, A Hirsch, M Scheloske… - … A European Journal, 2003 - Wiley Online Library
Control over the interchromophore separation, their angular relationship, and the spatial
overlap of their electronic clouds in several ZnP–C60 dyads (ZnP= zinc porphyrin) is used to …

Artificial molecular motors powered by light

A Credi - Australian journal of chemistry, 2006 - CSIRO Publishing
The bottom-up construction and operation of machines and motors of molecular size is a
topic of great interest in nanoscience, and a fascinating challenge of nanotechnology. The …

Phenothiazine− pyrene dyads: Photoinduced charge separation and structural relaxation in the CT state

N Acar, J Kurzawa, N Fritz, A Stockmann… - The Journal of …, 2003 - ACS Publications
Electron donor− acceptor systems with phenothiazine linked directly to pyrene exhibit a dual
emission in moderately and very polar solvents. Steady state and time-resolved …

[PDF][PDF] Orbital interactions and long-range electron transfer

MN Paddon-Row - Advances in physical organic chemistry, 2003 - academia.edu
ADVANCES IN PHYSICAL ORGANIC CHEMISTRY Copyright q 2003 Elsevier Science Ltd
VOLUME 38 ISSN 0065-3160 DOI 10.1016/S0065-3160 (03) 38001-3 All rights reserved …