Single-atom catalysts across the periodic table

SK Kaiser, Z Chen, D Faust Akl, S Mitchell… - Chemical …, 2020 - ACS Publications
Isolated atoms featuring unique reactivity are at the heart of enzymatic and homogeneous
catalysts. In contrast, although the concept has long existed, single-atom heterogeneous …

Toward active-site tailoring in heterogeneous catalysis by atomically precise metal nanoclusters with crystallographic structures

R Jin, G Li, S Sharma, Y Li, X Du - Chemical Reviews, 2020 - ACS Publications
Heterogeneous catalysis involves solid-state catalysts, among which metal nanoparticles
occupy an important position. Unfortunately, no two nanoparticles from conventional …

Atomically precise alloy nanoclusters: syntheses, structures, and properties

X Kang, Y Li, M Zhu, R Jin - Chemical Society Reviews, 2020 - pubs.rsc.org
Metal nanoclusters fill the gap between discrete atoms and plasmonic nanoparticles,
providing unique opportunities for investigating the quantum effects and precise structure …

Recent advances of single‐atom‐alloy for energy electrocatalysis

T Shen, S Wang, T Zhao, Y Hu… - Advanced Energy …, 2022 - Wiley Online Library
Abstract Single‐atom‐alloys (SAAs), as an emerging kind of materials, combine the
advantages of alloy and single‐atom catalysts. The full atomic utilization of active sites and …

Atomically precise noble metal nanoclusters as efficient catalysts: a bridge between structure and properties

Y Du, H Sheng, D Astruc, M Zhu - Chemical reviews, 2019 - ACS Publications
Improving the knowledge of the relationship between structure and properties is
fundamental in catalysis. Recently, researchers have developed a variety of well-controlled …

Selective Electrochemical H2O2 Production through Two‐Electron Oxygen Electrochemistry

Y Jiang, P Ni, C Chen, Y Lu, P Yang… - Advanced Energy …, 2018 - Wiley Online Library
Direct electrochemical production of hydrogen peroxide (H2O2) through two‐electron
oxygen electrochemistry, for example, the oxygen reduction in fuel cells or water oxidation in …

Advances of atomically dispersed catalysts from single-atom to clusters in energy storage and conversion applications

Y Wang, X Cui, J Zhang, J Qiao, H Huang, J Shi… - Progress in Materials …, 2022 - Elsevier
Owing to the special structural characteristics and maximized efficiency, atomically
dispersed catalysts (ADCs) with different atom sizes ranged from the single atom to clusters …

Molecular reactivity of thiolate-protected noble metal nanoclusters: synthesis, self-assembly, and applications

Q Yao, Z Wu, Z Liu, Y Lin, X Yuan, J Xie - Chemical Science, 2021 - pubs.rsc.org
Thiolate-protected noble metal (eg, Au and Ag) nanoclusters (NCs) are ultra-small particles
with a core size of less than 3 nm. Due to the strong quantum confinement effects and …

Single-atom catalysts for electrochemical energy storage and conversion

W Ma, H Wan, L Zhang, JY Zheng, Z Zhou - Journal of Energy Chemistry, 2021 - Elsevier
The expedited consumption of fossil fuels has triggered broad interest in the fabrication of
novel catalysts for electrochemical energy storage and conversion. Especially, single-atom …

Platinum single-atom catalysts: a comparative review towards effective characterization

Q Liu, Z Zhang - Catalysis Science & Technology, 2019 - pubs.rsc.org
Single-atom catalysis is a new frontier in the heterogeneous catalysis field due to its high
activity and selectivity for various catalytic reactions. However, decades ago, single-atom …