Much interest has been evinced on the properties of weakly bound van der Waals
complexes of π-systems because of their utility in diverse fields (Figure 1). 1-14 Theoretical …

Molecular clusters are nowadays preferred model systems to study both the energetics and
dynamics of molecules in a tailored molecular environment. 1-5 For the physical chemist …

Understanding the energy it takes to build or break chemical bonds is essential for scientists
and engineers in a wide range of innovative fields, including catalysis, nanomaterials …

We present calculations for the nonbonded interactions in the dimeric complexes: methane
dimer, ammonia dimer, water dimer, H2O⊙(NH3), CH4⊙(NH3), and (FHF)-as a function of …

A wealth of structural and dynamical information has been obtained in the last 30 years from
the study of high-resolution spectra of molecular clusters generated in a cold supersonic …

Efficient and stable electrocatalysts for the hydrogen evolution reaction (HER) in alkaline
media at high current densities are necessary for industrial H2 production. Herein, the …

A study was made of X—H⋯ F—C interactions (X= N or O) in small-molecule crystal
structures. It was primarily based on 6728 structures containing X—H and C—F and no atom …

We present a comparative study on the nature and strength of weak hydrogen bonding
between the C (sp3) H, C (sp2) H, and C (sp) H donor bonds and F C (sp3) acceptors …

Recently reported rotational spectroscopic studies on small dimers and oligomers bound by
weak hydrogen bonds show that the driving forces, the spatial arrangement and the …

Selective aromatic fluorine substitution can increase the affinity of a molecule for a
macromolecular recognition site through non-covalent interactions. These effects are …