Desulfonylation via radical process: recent developments in organic synthesis

XQ Chu, D Ge, YY Cui, ZL Shen, CJ Li - Chemical reviews, 2021 - ACS Publications
As the “chemical chameleon”, sulfonyl-containing compounds and their variants have been
merged with various types of reactions for the efficient construction of diverse molecular …

Sulfones as Chemical Chameleons: Versatile Synthetic Equivalents of Small‐Molecule Synthons

BM Trost, CA Kalnmals - Chemistry–A European Journal, 2019 - Wiley Online Library
Sulfones are flexible functional groups that can act as nucleophiles, electrophiles, or even
radicals. Changing the reaction conditions can completely alter the reactivity of a sulfonyl …

[HTML][HTML] Photocatalytic three-component asymmetric sulfonylation via direct C(sp3)-H functionalization

S Cao, W Hong, Z Ye, L Gong - Nature Communications, 2021 - nature.com
The direct and selective C (sp3)-H functionalization of cycloalkanes and alkanes is a highly
useful process in organic synthesis owing to the low-cost starting materials, the high step …

Visible-Light-Mediated Regioselective Chlorosulfonylation of Alkenes and Alkynes: Introducing the Cu(II) Complex [Cu(dap)Cl2] to Photochemical ATRA Reactions

A Hossain, S Engl, E Lutsker, O Reiser - ACS Catalysis, 2018 - ACS Publications
A visible-light-mediated photocatalyzed protocol utilizing copper–phenanthroline-based
catalysts has been developed that can convert a large number of olefins into their …

Asymmetric organocatalytic cyclization and cycloaddition reactions

A Moyano, R Rios - Chemical Reviews, 2011 - ACS Publications
The stereocontrolled construction of chiral carbo-and heterocycles is a topic of paramount
importance in modern organic synthesis, driven by the predominance of chiral mono-and …

Recent advances in organocatalytic methods for the synthesis of disubstituted 2-and 3-indolinones

R Dalpozzo, G Bartoli, G Bencivenni - Chemical Society Reviews, 2012 - pubs.rsc.org
In recent years, organocatalysis has enhanced its importance as a tool for the synthesis of
enantiomerically enriched compounds. Among the candidates for organocatalysis, the …

Recent applications of vinyl sulfone motif in drug design and discovery

R Ahmadi, S Emami - European Journal of Medicinal Chemistry, 2022 - Elsevier
Vinyl sulfone with electrophilic character is not only a versatile building block for various
organic transformations but also is a key structural unit in a large number of biologically …

Organocatalytic carbon–sulfur bond-forming reactions

P Chauhan, S Mahajan, D Enders - Chemical reviews, 2014 - ACS Publications
Carbon− heteroatom bond formations are very important reactions in organic synthesis and
have attracted the interest of many synthetic organic chemists, leading them to develop new …

Organoelement chemistry: Promising growth areas and challenges

GA Abakumov, AV Piskunov… - Russian Chemical …, 2018 - iopscience.iop.org
The chemistry of organoelement compounds is now one of the most rapidly developing
fields of research, regarding both fundamental science and solution of applied problems …

Progress in Photoinduced Radical Reactions using Electron Donor‐Acceptor Complexes

L Zheng, L Cai, K Tao, Z Xie, YL Lai… - Asian Journal of …, 2021 - Wiley Online Library
Photocatalyzed organic synthesis transformation is a remarkable green synthetic strategy
because of the advantages of operational simplicity, high chemoselectivities, cheap, and …