Asymmetrical Dependence of {Ba2+}:{SO42–} on BaSO4 Crystal Nucleation and Growth in Aqueous Solutions: A Dynamic Light Scattering Study

SYMH Seepma, BWM Kuipers, M Wolthers - ACS omega, 2023 - ACS Publications
The impact of solution stoichiometry, upon formation of BaSO4 crystals in 0.02 M NaCl
suspensions, on the development of particle size was investigated using dynamic light …

Barium isotope signatures of barite–fluid ion exchange in Equatorial Pacific sediments

JT Middleton, A Paytan, M Auro, MA Saito… - Earth and Planetary …, 2023 - Elsevier
The isotope composition of barium (Ba) in the mineral barite (BaSO 4) is emerging as a
powerful tracer of the pelagic Ba, carbon, and sulfur cycles. However, it is critical to identify …

Barium isotope (re-) equilibration in the barite-fluid system and its implications for marine barite archives

K van Zuilen, AL Harrison, JA Stammeier… - Earth and Planetary …, 2023 - Elsevier
Variations in the Ba isotopic composition of seawater are largely driven by the extent of
barite precipitation in the marine photic zone and replenishment of Ba by upwelling and/or …

Barium isotope fractionation in barite–fluid systems at chemical equilibrium

JT Middleton, WL Hong, A Paytan, ME Auro, EM Griffith… - Chemical …, 2023 - Elsevier
The barium isotope composition of sedimentary barite (BaSO 4, barium sulfate) is emerging
as a powerful tracer of the sources and cycling of Ba in modern and ancient marine …

Coupled feldspar dissolution and secondary mineral precipitation in batch systems: 6. Labradorite dissolution, calcite growth, and clay precipitation at 60° C and pH …

M Chen, L Gong, J Schott, P Lu, K Chen, H Yuan… - … et Cosmochimica Acta, 2025 - Elsevier
We conducted experiments on concurrent labradorite dissolution, calcite precipitation, and
clay precipitation in batch reactor systems and tracked reaction processes using multiple …

Reaction order of near equilibrium calcite dissolution: Uncertainties and ambiguities of isotopic tracer methods

DJ DePaolo, S Zhang - Geochimica et Cosmochimica Acta, 2024 - Elsevier
Dissolution of calcite in water is fundamental to geochemistry. Laboratory methods generally
give consistent dissolution rates under conditions far from equilibrium, but close to …

Effect of Solution Stoichiometry on BaSO4 Crystallization from Turbidity Measurements and Modeling

VFD Peters, A Baken, S Seepma… - Industrial & …, 2023 - ACS Publications
The impact of solution stoichiometry on the nucleation and growth of BaSO4 was studied by
measuring solution transmittance and subsequent fitting to a crystallization model. Our …

The impact of stoichiometry on the initial steps of crystal formation: Stability and lifetime of charged triple‐ion complexes

JA Koskamp, SYMH Seepma… - … A European Journal, 2024 - Wiley Online Library
Minerals form in natural systems from solutions with varying ratios of their lattice ions, yet
non‐stoichiometric conditions have generally been overlooked in investigations of new …

[PDF][PDF] Assessing an aqueous flow cell designed for in situ crystal growth under X-ray nanotomography and effects of radiolysis products

K Yuan, V Starchenko, N Rampal, F Yang… - Journal of …, 2023 - journals.iucr.org
Nucleation and growth of minerals has broad implications in the geological, environmental
and materials sciences. Recent developments in fast X-ray nanotomography have enabled …

Barium isotope cycling in the marine environment: Pathways of fractionation and implications for paleoceanographic applications

JT Middleton - 2022 - dspace.mit.edu
Removal of particulate organic carbon (POC) from sunlit surface waters into the deep ocean
represents a climatically important sink of atmospheric carbon dioxide (CO₂), linking the …