Molecular carbons: How far can we go?

MW Wang, W Fan, X Li, Y Liu, Z Li, W Jiang, J Wu… - Acs Nano, 2023 - ACS Publications
The creation and development of carbon nanomaterials promoted material science
significantly. Bottom-up synthesis has emerged as an efficient strategy to synthesize …

Helicenes: synthesis and applications

Y Shen, CF Chen - Chemical reviews, 2012 - ACS Publications
Helicenes are polycyclic aromatic compounds with nonplanar screw-shaped skeletons
formed by ortho-fused benzene or other aromatic rings. 1, 2 The first helicenes 1 and 2 …

Geodesic polyarenes by flash vacuum pyrolysis

VM Tsefrikas, LT Scott - Chemical reviews, 2006 - ACS Publications
Geodesic polyarenes constitute a rapidly growing family of polycyclic aromatic hydrocarbons
(PAHs) that resemble the geodesic domes of the great 20th century American architect …

Synthesis, structures, and properties of π-extended double helicene: a combination of planar and nonplanar π-systems

T Fujikawa, Y Segawa, K Itami - Journal of the American Chemical …, 2015 - ACS Publications
The synthesis, structures, and properties of a π-extended double helicene 1 are described.
This double helicene 1 was synthesized by a four-fold oxidative C–H biphenylation of …

Synthesis, structures, and properties of hexapole helicenes: assembling six [5] helicene substructures into highly twisted aromatic systems

T Hosokawa, Y Takahashi, T Matsushima… - Journal of the …, 2017 - ACS Publications
Hexapole helicenes 1, which contain six [5] helicene substructures, were synthesized by Pd-
catalyzed [2+ 2+ 2] cycloadditions of aryne precursor 6. Among the possible 20 …

Ball-, bowl-, and belt-shaped conjugated systems and their complexing abilities: exploration of the concave− convex π− π interaction

T Kawase, H Kurata - Chemical reviews, 2006 - ACS Publications
Since the discovery of buckminsterfullerene C60 (Chart 1) by Kroto, Smalley, and Curl, 1-4 a
number of reports concerning new carbon allotropes having a variety of threedimensional …

A Rational Chemical Synthesis of C60

LT Scott, MM Boorum, BJ McMahon, S Hagen, J Mack… - Science, 2002 - science.org
Isolable quantities of C60, the smallest stable fullerene, have been synthesized in 12 steps
from commercially available starting materials by rational chemical methods. A molecular …

A molecular bowl sumanene

T Amaya, T Hirao - Chemical Communications, 2011 - pubs.rsc.org
Nonplanar polyaromatic carbon molecules including fullerenes and carbon nanotubes have
been attracting great interest due to their potential as materials, catalysts, etc. In this context …

Methods for the chemical synthesis of fullerenes

LT Scott - Angewandte Chemie International Edition, 2004 - Wiley Online Library
C60 has been synthesized by chemical methods in 12 steps. Lessons learned in the
author's laboratory during a decade devoted to the synthesis and study of open geodesic …

Lithium-Mediated Mechanochemical Cyclodehydrogenation

K Fujishiro, Y Morinaka, Y Ono, T Tanaka… - Journal of the …, 2023 - ACS Publications
Cyclodehydrogenation is an essential synthetic method for the preparation of polycyclic
aromatic hydrocarbons, polycyclic heteroaromatic compounds, and nanographenes. Among …