The enantioselective synthesis of spirocycles has long been pursued by organic chemists.
Despite their unique 3D properties and presence in several natural products, the difficulty in …

The construction of carbon− carbon bonds, along with the creation of stereogenic carbon
centers, continues to be an appealing and demanding area of research, and processes in …

The catalytic enantioselective assembly of spirocyclic molecules featuring a spiro quaternary
carbon stereocenter is currently of great interest because such privileged 3D structures are …

Particular success has been achieved in the synthesis of new products and in processes
since the twelve principles of “green chemistry” were formulated in the 1990s. These …

An efficient method for the diastereo‐and enantioselective construction of vicinal all‐carbon
quaternary stereocenters through palladium‐catalyzed decarboxylative cycloaddition of …

Covering: 2000 to 2015 Molecules containing vicinal all-carbon quaternary stereocenters
are found in many secondary metabolites, and they exhibit a variety of biological and …

This review summarizes the advances in the catalytic enantioselective construction of vicinal
quaternary carbon stereocenters, introduces major synthetic strategies and discusses their …

Sustainability in chemical synthesis is a major aspect of the current synthetic endeavors and,
therefore, mimicking the biological process in the laboratory nowadays has the highest …

Both physical and organic chemists are interested in the cyclopropane ring, the former
owing to the strain inherent to the small ring structure, the latter prompted by the importance …

We report the use of a two-fold Pd-catalyzed decarboxylative allylic alkylation (Pd-DAAA) to
construct two vicinal all carbon quaternary stereocenters in a diastereo-and enantioselective …