[HTML][HTML] The shape of porphyrins

CJ Kingsbury, MO Senge - Coordination Chemistry Reviews, 2021 - Elsevier
Porphyrin molecules are a widely exploited biochemical moiety, with uses in medicinal
chemistry, sensing and materials science. The shape of porphyrins, as an aromatic unit, is …

Nonplanar porphyrins: synthesis, properties, and unique functionalities

T Ishizuka, N Grover, CJ Kingsbury, H Kotani… - Chemical Society …, 2022 - pubs.rsc.org
Porphyrins are variously substituted tetrapyrrolic macrocycles, with wide-ranging biological
and chemical applications derived from metal chelation in the core and the 18π aromatic …

Hydrogen evolution catalyzed by corrole-chelated nickel complexes, characterized in all catalysis-relevant oxidation states

QC Chen, S Fite, N Fridman, B Tumanskii… - ACS …, 2022 - ACS Publications
Designing catalysts that are not based on precious metals remains a major research priority
worldwide, particularly for the feasible production of hydrogen gas. Given the increasing …

2D/3D covalent organic frameworks based on cobalt corroles for CO binding

J Yang, L André, N Desbois, CP Gros… - Materials Today Chemistry, 2023 - Elsevier
In the present work, the synthesis, characterization, and gas adsorption properties of new 2D
covalent organic framework (COF)(2D-COF-Cor) and 3D COF (3D-COF-Cor) based on …

Structural modification of nickel tetra (thiocyano) corroles during electrochemical water oxidation

P Nayak, AK Singh, M Nayak, S Kar, K Sahu… - Dalton …, 2024 - pubs.rsc.org
In this study, we present two fully characterized nickel tetrathiocyanocorroles, representing a
novel class of 3d-metallocorroles. These nickel (II) ions form square planar complexes …

Do Corroles Stabilize Tetravalent Antimony?

S Eulberg, N Schulze, J Krumsieck… - Angewandte Chemie …, 2023 - Wiley Online Library
Antimony corrole cations have been prepared by one‐electron oxidation of antimony (III)
congeners with silver (I) and copper (II) salts. Isolation and crystallization was successful for …

Adsorbate Configurations in Ni Single-Atom Catalysts during Electrocatalytic Reduction Unveiled by Operando XAS, XES, and Machine Learning

A Martini, J Timoshenko, P Grosse, C Rettenmaier… - Physical Review Letters, 2024 - APS
Nickel and nitrogen co-doped carbon (Ni-NC) catalysts are attracting attention due to their
exceptionally high performance in the electrocatalytic reduction of CO 2 (CO 2 RR) to CO …

Nanostructured Aluminum Oxyhydroxide—A Prospective Support for Functional Porphyrin-Based Materials

SM Korobkov, KP Birin, AN Khodan, OY Grafov… - International Journal of …, 2023 - mdpi.com
A method for the grafting of unsymmetrical A2BC-type 5, 15-bis (4-butoxyphenyl)-10-(4-
carboxyphenyl)-20-(phenanthrenoimidazolyl)-porphyrin onto the surface of nanostructured …

X-ray absorption spectroscopy of exemplary platinum porphyrin and corrole derivatives: metal-versus ligand-centered oxidation

BD Matson, KE Thomas, AB Alemayehu, A Ghosh… - RSC …, 2021 - pubs.rsc.org
A combination of Pt L3-edge X-ray absorption spectroscopy (EXAFS and XANES) and DFT
(TPSS) calculations have been performed on powder samples of the archetypal platinum …

Why can cobalt (III) corrole form more stable metal/organic interfaces than cobalt (II) porphyrin?

J Herritsch, M Zugermeier, M Schmid… - Journal of Porphyrins …, 2023 - World Scientific
The ring size of tetrapyrrole ligands can dramatically influence the interfacial interactions of
their metal complexes, as was found in a comparison of alkyl-substituted cobalt (II) …