Beyond charge balance: counter‐cations in polyoxometalate chemistry

A Misra, K Kozma, C Streb… - Angewandte Chemie …, 2020 - Wiley Online Library
Polyoxometalates (POMs) are molecular metal‐oxide anions applied in energy conversion
and storage, manipulation of biomolecules, catalysis, as well as materials design and …

Dioxygen in polyoxometalate mediated reactions

IA Weinstock, RE Schreiber, R Neumann - Chemical reviews, 2017 - ACS Publications
In this review article, we consider the use of molecular oxygen in reactions mediated by
polyoxometalates. Polyoxometalates are anionic metal oxide clusters of a variety of …

Structure, properties and reactivity of polyoxometalates: a theoretical perspective

X López, JJ Carbó, C Bo, JM Poblet - Chemical Society Reviews, 2012 - pubs.rsc.org
In the thematic review dedicated to polyoxometalate (POM) chemistry published in Chemical
Reviews in 1998, no contribution was devoted to theory. This is not surprising because …

Recent developments in the crystal engineering of diverse coordination modes (0–12) for Keggin-type polyoxometalates in hybrid inorganic–organic architectures

M Mirzaei, H Eshtiagh-Hosseini, M Alipour… - Coordination Chemistry …, 2014 - Elsevier
At present, research into polyoxometalates (POMs) is a hot topic in many scientific fields,
mainly because of their vast range of potential applications. Recently, the coordination …

New insights on the interaction of phenanthroline based ligands and metal complexes and polyoxometalates with duplex DNA and G-quadruplexes

Á Sánchez-González, NAG Bandeira… - Molecules, 2021 - mdpi.com
This work provides new insights from our team regarding advances in targeting canonical
and non-canonical nucleic acid structures. This modality of medical treatment is used as a …

Investigating the transformations of polyoxoanions using mass spectrometry and molecular dynamics

JM Cameron, L Vilà-Nadal, RS Winter… - Journal of the …, 2016 - ACS Publications
The reactions of [γ-SiW10O36] 8–represent one of the most important synthetic gateways
into a vast array of polyoxotungstate chemistry. Herein, we set about exploring the …

Facile and reproducible electrochemical synthesis of the giant polyoxomolybdates

MTK Ng, NL Bell, DL Long, L Cronin - Journal of the American …, 2021 - ACS Publications
Giant polyoxomolybdates are traditionally synthesized by chemical reduction of molybdate
in aqueous solutions, generating complex nanostructures such as the highly symmetrical …

Synthesis and characterization of multinuclear manganese-containing tungstosilicates

R Al-Oweini, BS Bassil, J Friedl, V Kottisch… - Inorganic …, 2014 - ACS Publications
The five manganese-containing, Keggin-based tungstosilicates [MnII3 (OH) 3 (H2O) 3 (A-α-
SiW9O34)] 7–(1),[MnIII3 (OH) 3 (H2O) 3 (A-α-SiW9O34)] 4–(2),[MnIII3 (OH) 3 (H2O) 3 (A-β …

Nucleation mechanisms and speciation of metal oxide clusters

E Petrus, M Segado, C Bo - Chemical Science, 2020 - pubs.rsc.org
The self-assembly mechanisms of polyoxometalates (POMs) are still a matter of discussion
owing to the difficult task of identifying all the chemical species and reactions involved. We …

Jenseits von Ladungsausgleich: Gegenkationen in der Polyoxometallat‐Chemie

A Misra, K Kozma, C Streb, M Nyman - Angewandte Chemie, 2020 - Wiley Online Library
Abstract Polyoxometallate (POMs) sind molekulare Metalloxidanionen, die Anwendung in
Energiewandlung und‐speicherung, biomolekularer Chemie sowie Materialdesign und …