3d transition metals for C–H activation

P Gandeepan, T Müller, D Zell, G Cera… - Chemical …, 2018 - ACS Publications
C–H activation has surfaced as an increasingly powerful tool for molecular sciences, with
notable applications to material sciences, crop protection, drug discovery, and …

Transition metal-catalyzed C–H bond functionalizations by the use of diverse directing groups

Z Chen, B Wang, J Zhang, W Yu, Z Liu… - Organic Chemistry …, 2015 - pubs.rsc.org
Transition metal-catalyzed direct functionalization of C–H bonds is one of the key emerging
strategies that is currently attracting tremendous attention with the aim to provide alternative …

Recent advances in directed C–H functionalizations using monodentate nitrogen-based directing groups

M Zhang, Y Zhang, X Jie, H Zhao, G Li… - Organic Chemistry …, 2014 - pubs.rsc.org
The use of directing groups has proven to be a successful strategy to enhance reactivity and
control selectivity in C–H functionalization reactions. In the past decade, a multitude of new …

Visible light-mediated CP bond formation reactions

BG Cai, J Xuan, WJ Xiao - Science Bulletin, 2019 - Elsevier
Organophosphorus compounds have attracted continuous attention in materials science,
agrochemical and pharmaceutical fields due to their unique bioactivities. Thus, the …

Thianthrenium-Enabled Phosphorylation of Aryl C–H Bonds via Electron Donor–Acceptor Complex Photoactivation

H Xu, X Li, Y Dong, S Ji, J Zuo, J Lv, D Yang - Organic Letters, 2023 - ACS Publications
An efficient strategy for the preparation of aryl phosphonates via blue-light-promoted single
electron transfer process of an EDA complex between phosphites and thianthrenium salts …

Construction of Axial Chirality by Rhodium‐Catalyzed Asymmetric Dehydrogenative Heck Coupling of Biaryl Compounds with Alkenes

J Zheng, SL You - Angewandte Chemie International Edition, 2014 - Wiley Online Library
Enantioselective construction of axially chiral biaryls by direct C H bond functionalization
reactions has been realized. Novel axially chiral biaryls were synthesized by the direct C H …

Copper‐Catalyzed Radical/Radical CH/PH Cross‐Coupling: α‐Phosphorylation of Aryl Ketone O‐Acetyloximes

J Ke, Y Tang, H Yi, Y Li, Y Cheng, C Liu… - Angewandte …, 2015 - Wiley Online Library
The selective radical/radical cross‐coupling of two different organic radicals is a great
challenge due to the inherent activity of radicals. In this paper, a copper‐catalyzed …

Silver-Mediated Oxidative C–H/P–H Functionalization: An Efficient Route for the Synthesis of Benzo[b]phosphole Oxides

YR Chen, WL Duan - Journal of the American Chemical Society, 2013 - ACS Publications
A Ag-mediated C–H/P–H functionalization reaction of arylphosphine oxides with internal
alkynes was described for the direct preparation of benzo [b] phosphole oxides with a high …

Scalable Rhodium (III)‐Catalyzed Aryl C− H Phosphorylation Enabled by Anodic Oxidation Induced Reductive Elimination

ZJ Wu, F Su, W Lin, J Song, TB Wen… - Angewandte …, 2019 - Wiley Online Library
Transition metal catalyzed C− H phosphorylation remains an unsolved challenge. Reported
methods are generally limited in scope and require stoichiometric silver salts as oxidants …

Electrochemical C–H phosphorylation of arenes in continuous flow suitable for late-stage functionalization

H Long, C Huang, YT Zheng, ZY Li, LH Jie… - Nature …, 2021 - nature.com
The development of efficient and sustainable methods for carbon-phosphorus bond
formation is of great importance due to the wide application of organophosphorus …