Because of its unique properties, water drives many natural and biological processes. While a detailed understanding of its precise role is still being unravelled, it is clear that the …
ML Horng, JA Gardecki, A Papazyan… - The Journal of …, 1995 - ACS Publications
Time-resolved emission measurements of the solute coumarin 153 (C153) are used to probe the time dependence of solvation in 24 common solvents at room temperature …
THE timescale of the response of solvent molecules to electronic rearrangement of solute molecules has a critical influence on the rates of chemical reactions in liquids1–10. In …
We investigated rearrangements of the hydrogen-bond network in water by measuring fluctuations in the OH-stretching frequency of HOD in liquid D2O with femtosecond infrared …
SK Pal, AH Zewail - Chemical Reviews, 2004 - ACS Publications
Almost all biological macromoleculessproteins (enzymes) and DNAsare inactive in the absence of water. Hydration of a protein/enzyme is particularly important for the stability of …
Water is in many aspects a remarkable liquid. Apart from its importance in biological processes and the extended use in chemistry as solvent, the exceptional properties of liquid …
M Maroncelli - Journal of Molecular Liquids, 1993 - Elsevier
The dynamics of solvation in polar liquids - ScienceDirect Skip to main contentSkip to article Elsevier logo Journals & Books Search RegisterSign in View PDF Download full issue …
Polar solvents often exert a dramatic influence on reactions in solution. Equilibrium aspects of this influence involve differential solvation of reactants compared to the transition state …
K Bhattacharyya - Accounts of chemical research, 2003 - ACS Publications
Water molecules confined in a supramolecular assembly control reactivity and dynamics of biological systems in a unique way. In a confined system, water molecules display an …