Organic synthesis using clay and clay-supported catalysts

G Nagendrappa - Applied Clay Science, 2011 - Elsevier
Clays and modified clays are used to catalyze various types of organic reactions such as
addition, Michael addition, carbene addition and insertion, hydrogenation, allylation …

K10 montmorillonite clays as environmentally benign catalysts for organic reactions

BS Kumar, A Dhakshinamoorthy… - Catalysis Science & …, 2014 - pubs.rsc.org
Montmorillonite is one of the most intensively explored catalytic materials in heterogeneous
catalysis due to its low cost and eco-friendliness. Also, it possesses some unique properties …

Catalytic asymmetric synthesis of silicon-stereogenic organosilanes

Y Wu, L Zheng, Y Wang, P Wang - Chem, 2023 - cell.com
Silicon-stereogenic organosilanes have attracted heightened attention in various scientific
communities including synthetic chemistry, material chemistry, and medicinal chemistry …

Copper-catalyzed desymmetrization of prochiral silanediols to silicon-stereogenic silanols

J Gao, PL Mai, Y Ge, W Yuan, Y Li, C He - ACS Catalysis, 2022 - ACS Publications
Despite the growing demand for the enantioenriched silicon-stereogenic silanols in
materials science, medicinal chemistry, and modern synthetic chemistry, the catalytic …

Synthesis of Si‐Stereogenic Silanols by Catalytic Asymmetric Hydrolytic Oxidation

W Yuan, X Zhu, Y Xu, C He - … Chemie International Edition, 2022 - Wiley Online Library
Despite growing progress in the construction of chiral organosilicon compounds, the
catalytic asymmetric synthesis of silicon‐stereogenic silanols is less explored and remains a …

Construction of chiral tetraorganosilicons by tandem desymmetrization of silacyclobutanes/intermolecular dehydrogenative silylation

QW Zhang, K An, LC Liu, Q Zhang, H Guo… - Angewandte …, 2017 - Wiley Online Library
We report a method to construct chiral tetraorganosilicons by tandem silacyclobutane (SCB)
desymmetrization–dehydrogenative silylations. A wide array of dibenzosiloles with …

Montmorillonite: An efficient, heterogeneous and green catalyst for organic synthesis

N Kaur, D Kishore - J. Chem. Pharm. Res, 2012 - hero.epa.gov
Reactions of organic molecules on Montmorillonite clay mineral have been investigated
from various aspects. These include catalytic reactions for organic synthesis, chemical …

Chiral silanols: strategies and tactics for their synthesis

J Gao, C He - Chemistry–A European Journal, 2023 - Wiley Online Library
Silanols are valuable and important compounds, which have found widespread applications
in the field of materials science, synthetic chemistry, and medicinal chemistry. Although a …

Rhodium-catalyzed carbon–silicon bond activation for synthesis of benzosilole derivatives

M Onoe, K Baba, Y Kim, Y Kita, M Tobisu… - Journal of the …, 2012 - ACS Publications
A rhodium-catalyzed coupling reaction of 2-trimethylsilylphenylboronic acid with internal
alkynes is developed for the synthesis of 2, 3-disubstituted benzosilole derivatives. A range …

Frustrated Lewis Pair-Promoted Organocatalytic Transformation of Hydrosilanes into Silanols with Water Oxidant

F Xie, S Zhang, M Yang, J He, S Li… - Journal of the American …, 2024 - ACS Publications
Owing to their unique properties, the silanols have attracted intense attention but remain
challenging to prepare from the organocatalytic oxidation of hydrosilanes using H2O as a …