Review of on-line and near real-time spectroscopic monitoring of processes relevant to nuclear material management

P Tse, SA Bryan, NP Bessen, AM Lines, JC Shafer - Analytica chimica acta, 2020 - Elsevier
Spectroscopic chemometric based on-line monitoring of used nuclear fuel (UNF)
reprocessing solutions and characterization of legacy nuclear waste (LNW) stored at …

[HTML][HTML] Analytical capabilities for iodine detection: Review of possibilities for different applications

BJ Riley, CL Beck, JS Evarts, S Chong, AM Lines… - AIP Advances, 2024 - pubs.aip.org
a) Authors to whom correspondence should be addressed: brian. riley@ pnnl. gov. Tel.:+ 1
(509) 372-4651; chelsie. beck@ pnnl. gov. Tel.:+ 1 (509) 371-7346; amanda. lines@ pnnl …

Exploring the Complex Chemistry of Uranium within Molten Chloride Salts

SD Branch, HM Felmy, A Schafer Medina… - Industrial & …, 2023 - ACS Publications
Harsh environments represent a unique opportunity to explore new frontiers in chemistry
while developing novel tools to meet global needs. Exploring the chemistry of uranium …

Sensor fusion: comprehensive real-time, on-line monitoring for process control via visible, near-infrared, and Raman spectroscopy

AM Lines, GB Hall, S Asmussen, J Allred, S Sinkov… - Acs …, 2020 - ACS Publications
On-line monitoring based on optical spectroscopy provides unprecedented insight into the
chemical composition of process streams or batches. Amplifying this approach through …

[HTML][HTML] Multivariate chemometric methods and Vis-NIR spectrophotometry for monitoring plutonium-238 anion exchange column effluent in a radiochemical hot cell

LR Sadergaski, KG Myhre, LH Delmau - Talanta Open, 2022 - Elsevier
Abstract The Plutonium-238 Supply Program at Oak Ridge National Laboratory has
developed the capability to inform process decisions during full-scale 238 Pu anion …

On-line monitoring of gas-phase molecular iodine using Raman and fluorescence spectroscopy paired with chemometric analysis

HM Felmy, AJ Clifford, AS Medina… - Environmental …, 2021 - ACS Publications
Molten salt reactors (MSRs) have the potential to safely support green energy goals while
meeting baseload energy needs with diverse energy portfolios. While reactor designers …

Online monitoring of solutions within microfluidic chips: simultaneous Raman and UV–vis absorption spectroscopies

GL Nelson, AM Lines, JM Bello, SA Bryan - ACS sensors, 2019 - ACS Publications
Microfluidics is an appealing analytical tool in the global effort to close the nuclear fuel cycle.
Using a microfluidic chip permits the analysis of greatly reduced sample volumes compared …

Online, Real-Time Analysis of Highly Complex Processing Streams: Quantification of Analytes in Hanford Tank Sample

AM Lines, P Tse, HM Felmy, JM Wilson… - Industrial & …, 2019 - ACS Publications
Processing of hazardous materials is a crucial example where online monitoring can
significantly reduce operation risk, cost, and time. This is particularly true in the case of the …

Practical guide to chemometric analysis of optical spectroscopic data

HE Lackey, RL Sell, GL Nelson, TA Bryan… - Journal of Chemical …, 2023 - ACS Publications
The methodology and mathematical treatment of several classic multivariate methods for the
analysis of spectroscopic data is demonstrated in a straightforward way that can be used as …

Unveiling the Reduction Mechanism of Pu (IV) by Acetaldoxime

XB Li, QY Wu, CZ Wang, JH Lan, M Zhang… - The Journal of …, 2023 - ACS Publications
The separation of plutonium (Pu) from spent nuclear fuel was achieved by effectively
adjusting the oxidation state of Pu from+ IV to+ III in the plutonium uranium reduction …