T Satyanarayana, S Abraham… - Angewandte Chemie …, 2009 - Wiley Online Library
There is a need for the preparation of enantiomerically pure compounds for various applications. An efficient approach to achieve this goal is asymmetric catalysis. The chiral …
A El Kadib - ChemSusChem, 2015 - Wiley Online Library
Increased demand for more sustainable materials and chemical processes has tremendously advanced the use of polysaccharides, which are natural biopolymers, in …
T Marcelli, H Hiemstra - Synthesis, 2010 - thieme-connect.com
This article reviews the applications of cinchona alkaloids as asymmetric catalysts. In the last few years, characterized by the resurgence of interest in asymmetric organocatalysis …
The classical Henry reaction, the coupling of a nitroalkane with a carbonyl compound in the presence of a base, is an important C–C bond forming reaction in organic chemistry giving β …
H Li, B Wang, L Deng - Journal of the American Chemical Society, 2006 - ACS Publications
The development of highly enantioselective and general catalytic nitroaldol (Henry) reactions with ketones is a challenging yet desirable task in organic synthesis. In this …
The development of highly efficient and enantioselective heterogeneous catalysts based on earth-abundant elements and inexpensive chiral ligands is essential for environment …
Zinc is the 24th most abundant element in the Earth's crust. Since the discovery of pure zinc metal in the 18th century, the main application of zinc metal is as materials. Because zinc …
Enantioselectivity values represent relative rate measurements that are sensitive to the structural features of the substrates and catalysts interacting to produce them. Therefore …