Recent Advancements in the Utilization of s-Block Organometallic Reagents in Organic Synthesis with Sustainable Solvents
MJ Rodríguez-Álvarez, N Ríos-Lombardía… - Molecules, 2024 - mdpi.com
This mini-review offers a comprehensive overview of the advancements made over the last
three years in utilizing highly polar s-block organometallic reagents (specifically, RLi, RNa …
three years in utilizing highly polar s-block organometallic reagents (specifically, RLi, RNa …
Harnessing Deep Eutectic Solvents for Regioselective Polar Additions to α, βUnsaturated Ketones and Aldehydes
Advancing the use of air‐sensitive polar organometallic Grignard and organolithium
reagents under more environmentally benign conditions, here we report the addition of …
reagents under more environmentally benign conditions, here we report the addition of …
Visible‐Light Activation of Diorganyl Bis (pyridylimino) Isoindolide Aluminum (III) Complexes and Their Organometallic Radical Reactivity
JO Wenzel, J Werner, A Allgaier… - Angewandte Chemie …, 2024 - Wiley Online Library
We report on the synthesis and characterization of a series of (mostly) air‐stable diorganyl
bis (pyridylimino) isoindolide (BPI) aluminum complexes and their chemistry upon visible …
bis (pyridylimino) isoindolide (BPI) aluminum complexes and their chemistry upon visible …
A heterogeneous chemoenzymatic route toward the continuous transformation of γ-alkynoic acids into γ-hydroxy acids
J Santiago-Arcos, D Andrés-Sanz… - Cell Reports Physical …, 2024 - cell.com
The combination of chemocatalysts and biocatalysts enables access to synthetic routes that
would otherwise be elusive when using either catalyst type in isolation. However, most …
would otherwise be elusive when using either catalyst type in isolation. However, most …
Aktivierung von Diorganyl‐bis (pyridylimino) isoindolid‐Aluminiumkomplexen mit sichtbarem Licht und deren organometallische Radikalreaktivität
JO Wenzel, J Werner, A Allgaier… - Angewandte …, 2024 - Wiley Online Library
Wir berichten über die Synthese und Charakterisierung einer Reihe von weitgehend
luftstabilen Diorganyl‐bis (pyridylimino) isoindolid (BPI)− Aluminiumkomplexen und deren …
luftstabilen Diorganyl‐bis (pyridylimino) isoindolid (BPI)− Aluminiumkomplexen und deren …
Merging Organolithium Chemistry and Stereoselective Biocatalysis: Transformation of Aromatic Nitriles into Chiral Alcohols
N Ríos‐Lombardía, G Morís‐Menéndez… - Advanced Synthesis …, 2024 - Wiley Online Library
The combination of RLi‐mediated organic transformations (under air and at room
temperature) with a subsequent stereoselective biocatalytic reaction is for the first time …
temperature) with a subsequent stereoselective biocatalytic reaction is for the first time …
Synergistic One‐pot Tandem Combination of Cu and Proline Catalysis: Stereodivergent Synthesis of Chiral Aldols from Primary Alcohols
M López‐Aguilar, M Ramos‐Martín… - …, 2024 - Wiley Online Library
A new stereodivergent one‐pot tandem protocol, which granted diastereo‐and
enantioselective access to chiral aldols by starting from simple primary alcohols, is …
enantioselective access to chiral aldols by starting from simple primary alcohols, is …