A Zn benzotriazolate metal–organic framework (MOF),[Zn (ZnO2CCH3) 4 (bibta) 3](1, bibta2– = 5, 5′-bibenzotriazolate), has been subjected to a mild CH3CO2–/HCO3–ligand …
This perspective article provides an overview of the advancements in the field of non- precious metal complexes featuring anionic PCP pincer ligands with the inclusion of …
F Lin, JL Yu, Y Shen, SQ Zhang… - Journal of the …, 2018 - ACS Publications
A series of cage penta-arylated carboranes have been synthesized by palladium-catalyzed intermolecular coupling of the C-carboxylic acid of the monocarba-closo-dodecaborate …
AH Mousa, AV Polukeev, J Hansson, OF Wendt - Organometallics, 2020 - ACS Publications
The synthesis of a new unsymmetrical PCN ligand bearing tert-butyl groups on the phosphorus atom and isopropyl groups on the nitrogen donor atom is presented. It reacts …
A terminal nickel hydroxide complex (PN3P) Ni (OH)(3) bearing the 2nd generation phosphorus–nitrogen PN3P-pincer ligand has been synthesized and structurally …
A nickel (II) hydroxo complex (3) supported by a cyclohexyl based POC sp3 OP pincer ligand (POC sp3 OP= cis-1, 3-Bis-(di-tert-butylphosphinito) cyclohexyl) is reported. Complex …
LM Martínez-Prieto, P Palma, E Álvarez… - Inorganic …, 2017 - ACS Publications
A series of nickel pincer complexes with terminal alkoxo ligands [(iPrPCP) Ni-OR](R= Et, n Bu, i Pr, CH2CH2OH; iPrPCP is the 2, 6-bis (diisopropylphosphinomethyl) phenyl pincer …
JE Heimann, WH Bernskoetter, JA Guthrie… - …, 2018 - ACS Publications
The insertion of CO2 into metal–element σ bonds such as M–H, M–OH, and M–NH2 is often proposed to be a key step in catalytic CO2 conversion. Nevertheless, there are few …
A Rivas Marquina, F Movilla… - … Section B: Structural …, 2020 - journals.iucr.org
The formation of the symmetrical μ3-carbonate-bridged self-assembled trinuclear NiII complex Na2 {[Ni (LO) 2 (H2O)] 3 (μ3-CO3)}(LO is the carboxylate anion of a l-tyrosine …