Utilization of Low-Concentration CO2 with Molecular Catalysts Assisted by CO2-Capturing Ability of Catalysts, Additives, or Reaction Media

Y Yamazaki, M Miyaji, O Ishitani - Journal of the American …, 2022 - ACS Publications
Increasing concentration of atmospheric CO2 is a worldwide concern and continues to
trigger various environmental problems. Photo-or electrocatalytic CO2 reduction (CO2-Red) …

Bioinspired Metal–Organic Framework for Trace CO2 Capture

CE Bien, KK Chen, SC Chien, BR Reiner… - Journal of the …, 2018 - ACS Publications
A Zn benzotriazolate metal–organic framework (MOF),[Zn (ZnO2CCH3) 4 (bibta) 3](1, bibta2–
= 5, 5′-bibenzotriazolate), has been subjected to a mild CH3CO2–/HCO3–ligand …

Non-precious metal complexes with an anionic PCP pincer architecture

S Murugesan, K Kirchner - Dalton Transactions, 2016 - pubs.rsc.org
This perspective article provides an overview of the advancements in the field of non-
precious metal complexes featuring anionic PCP pincer ligands with the inclusion of …

Palladium-catalyzed selective five-fold cascade arylation of the 12-vertex monocarborane anion by B–H activation

F Lin, JL Yu, Y Shen, SQ Zhang… - Journal of the …, 2018 - ACS Publications
A series of cage penta-arylated carboranes have been synthesized by palladium-catalyzed
intermolecular coupling of the C-carboxylic acid of the monocarba-closo-dodecaborate …

Carboxylation of the Ni–Me Bond in an Electron-Rich Unsymmetrical PCN Pincer Nickel Complex

AH Mousa, AV Polukeev, J Hansson, OF Wendt - Organometallics, 2020 - ACS Publications
The synthesis of a new unsymmetrical PCN ligand bearing tert-butyl groups on the
phosphorus atom and isopropyl groups on the nitrogen donor atom is presented. It reacts …

Monomeric nickel hydroxide stabilized by a sterically demanding phosphorus–nitrogen PN 3 P-pincer ligand: synthesis, reactivity and catalysis

C Yao, P Chakraborty, E Aresu, H Li, C Guan… - Dalton …, 2018 - pubs.rsc.org
A terminal nickel hydroxide complex (PN3P) Ni (OH)(3) bearing the 2nd generation
phosphorus–nitrogen PN3P-pincer ligand has been synthesized and structurally …

Synthesis and characterisation of POCsp3OP supported Ni (II) hydroxo, hydroxycarbonyl and carbonate complexes

KJ Jonasson, AH Mousa, OF Wendt - Polyhedron, 2018 - Elsevier
A nickel (II) hydroxo complex (3) supported by a cyclohexyl based POC sp3 OP pincer
ligand (POC sp3 OP= cis-1, 3-Bis-(di-tert-butylphosphinito) cyclohexyl) is reported. Complex …

Nickel Pincer Complexes with Frequent Aliphatic Alkoxo Ligands [(iPrPCP)Ni-OR] (R = Et, nBu, iPr, 2-hydroxyethyl). An Assessment of the Hydrolytic Stability of …

LM Martínez-Prieto, P Palma, E Álvarez… - Inorganic …, 2017 - ACS Publications
A series of nickel pincer complexes with terminal alkoxo ligands [(iPrPCP) Ni-OR](R= Et, n
Bu, i Pr, CH2CH2OH; iPrPCP is the 2, 6-bis (diisopropylphosphinomethyl) phenyl pincer …

Effect of Nucleophilicity on the Kinetics of CO2 Insertion into Pincer-Supported Nickel Complexes

JE Heimann, WH Bernskoetter, JA Guthrie… - …, 2018 - ACS Publications
The insertion of CO2 into metal–element σ bonds such as M–H, M–OH, and M–NH2 is often
proposed to be a key step in catalytic CO2 conversion. Nevertheless, there are few …

[PDF][PDF] Nickel (II) complexes based on L-amino-acid-derived ligands: synthesis, characterization and study of the role of the supramolecular structure in carbon dioxide …

A Rivas Marquina, F Movilla… - … Section B: Structural …, 2020 - journals.iucr.org
The formation of the symmetrical μ3-carbonate-bridged self-assembled trinuclear NiII
complex Na2 {[Ni (LO) 2 (H2O)] 3 (μ3-CO3)}(LO is the carboxylate anion of a l-tyrosine …