As “chemical chameleons,” organosulfones have been widely applied in various
desulfonylative functionalization reactions. However, the desulfonylative functionalization of …

Transition metal-catalyzed reductive difunctionalization of alkenes with alkyl halides is a
powerful method for upgrading commodity chemicals into densely functionalized molecules …

The divergent reductive cross-coupling with an ambident electrophile is rare. Previously, we
demonstrated a nickel-catalyzed reductive 2-pyridination of aryl iodides with difluoromethyl …

Herein, we demonstrate for the first time that coumarins derived from [2.2] paracyclophane
(pCp) can act as effective organo-photocatalysts and promote the reductive cleavage of …

The photoexcitation of 4-alkyl-1, 4-dihydropyridines (alkyl-DHPs) in the presence of a base
triggers the single-electron-transfer-mediated desulfonative radical-cross-coupling (RCC) …

Developing efficient and novel methodologies to construct a C–C bond is highly important in
both synthetic chemistry and pharmaceutical sciences. In recent years, the visible light …

Hantzsch ester (HEH) is a bench‐stable compound used in hydrogenation and
photoinduced reactions, where it acts as a photoreductant and an electron donor. In this …

[2.2] Paracyclophane-fused heterocycles represent an important scaffold. Traditional
approaches often suffer from tedious synthetic routes, and the development of catalytic …

In this study, we propose heavy-metal-free reductive coupling of arylacetylenes with
benzothiazole sulfones. The reactions of alkyl or benzylic benzothiazole sulfones with …

Herein, we disclosed a protocol for the deoxygenation of allyl arylsulfones to access the
corresponding thioethers under photoredox conditions by a “cut-sew” strategy. The key to …