The term helicate was introduced by Lehn and coworkers in 1987 for the description of a
polymetallic helical double-stranded complex, in effect a metalcontaining helix. 1 It is formed …

The self-assembly of helicate-type coordination compounds from oligodentate ligands and
two or more metal ions is an important part of metallo-supramolecular chemistry. The design …

Surface patterning of liquid metals (LMs) is a key processing step for LM‐based functional
systems. Current patterning methods are substrate specific and largely suffer from undesired …

Supramolecular chemistry describes the spontaneous assembly of noncovalently linked
molecular clusters of unique shape and composition and requires both a driving force and a …

There are numerous examples of supramolecular assemblies based on metal–ligand
interactions. Many have been synthesized unintentionally, while others have been the result …

Remarkable progress in the synthetic chemistry of supramolecular assemblies has created
many new structural types. With the proliferation of new structures has come increasing …

Recent investigations from our laboratory have described compelling experimental evidence
that Schiff-based pyridine, bipyridine (bipy), terpyridine (terpy), phenanthroline (phen) …

This study offers a detailed mechanistic investigation of host–guest encapsulation behavior
in a new enzyme–mimetic metal–ligand host and provides the first observation of a …

Silybin, a natural occurring flavolignan isolated from the fruits of Silibum marianum, has
been reported to exert antioxidant and free radical scavenging abilities. It was suggested to …

In coordination chemistry, the simplest supramolecular architecture is the two-metal-center
helicate. 1 As a result of a spontaneous, self-assembling process in which ligands wrap …