Visible light-promoted reactions with diazo compounds: a mild and practical strategy towards free carbene intermediates

Z Yang, ML Stivanin, ID Jurberg… - Chemical Society …, 2020 - pubs.rsc.org
Carbenes are important intermediates in organic chemistry and have been widely applied in
various types of organic reactions, ranging from cycloaddition reactions and sigmatropic …

Unlocking novel reaction pathways of diazoalkanes with visible light

C Empel, C Pei, RM Koenigs - Chemical Communications, 2022 - pubs.rsc.org
Photochemistry has recently attracted the interest of synthetic chemists to conduct photolysis
reactions of diazoalkanes. In this feature article, we provide a concise overview on this field …

Blue light-promoted photolysis of aryldiazoacetates

ID Jurberg, HML Davies - Chemical science, 2018 - pubs.rsc.org
Aryldiazoacetates can undergo photolysis under blue light irradiation (460–490 nm) at room
temperature and under air in the presence of numerous trapping agents, such as styrene …

[HTML][HTML] Mechanistic analysis by NMR spectroscopy: A users guide

Y Ben-Tal, PJ Boaler, HJA Dale, RE Dooley… - Progress in nuclear …, 2022 - Elsevier
A 'principles and practice'tutorial-style review of the application of solution-phase NMR in the
analysis of the mechanisms of homogeneous organic and organometallic reactions and …

[PDF][PDF] Preparation of ester derivatives of fatty acids for chromatographic analysis

WW Christie - Advances in lipid methodology, 1993 - lipidmaps.org
The technique of gas chromatography (GC) revolutionized the study of lipids by making it
possible to determine the complete fatty acid composition of a lipid in a very short time [53] …

Thermal stabilization of TEMPO-oxidized cellulose

H Fukuzumi, T Saito, Y Okita, A Isogai - Polymer Degradation and Stability, 2010 - Elsevier
A partially C6-carboxylated cellulose with carboxylate content of 1.68 mmol/g was prepared
by 2, 2, 6, 6-tetramethylpiperidine-1-oxyl radical (TEMPO)-mediated oxidation of a softwood …

Derivatization reactions and reagents for gas chromatography analysis

F Orata - Advanced gas chromatography-Progress in agricultural …, 2012 - books.google.com
Derivatization reactions are meant to transform an analyte for detectability in Gas
Chromatography (GC) or other instrumental analytical methods. Derivatization in GC …

Scalable Synthesis of Degradable Copolymers Containing α-Lipoic Acid via Miniemulsion Polymerization

PT Morris, K Watanabe, KR Albanese… - Journal of the …, 2024 - ACS Publications
A robust method is described to synthesize degradable copolymers under aqueous
miniemulsion conditions using α-lipoic acid as a cheap and scalable building block. Simple …

Construction of α-Acyloxy Ketones via Photoredox-Catalyzed O–H Insertion of Sulfoxonium Ylides with Carboxylic Acids

Q Sun, Y Peng, Y Wang, X Bao - Organic Letters, 2023 - ACS Publications
Herein, a photoredox-catalyzed insertion of sulfoxonium ylides with carboxylic acids was
advanced under mild and simple conditions, offering a practical approach for preparing α …

Strobilurin biosynthesis in Basidiomycete fungi

R Nofiani, K de Mattos-Shipley, KE Lebe… - Nature …, 2018 - nature.com
Strobilurins from fungi are the inspiration for the creation of the β-methoxyacrylate class of
agricultural fungicides. However, molecular details of the biosynthesis of strobilurins have …