Polyacrylonitrile‐Coordinated Perovskite Solar Cell with Open‐Circuit Voltage Exceeding 1.23 V

C Chen, X Wang, Z Li, X Du, Z Shao… - Angewandte Chemie …, 2022 - Wiley Online Library
In solution‐processed organic–inorganic halide perovskite films, halide‐anion related
defects including halide vacancies and interstitial defects can easily form at the surfaces and …

A Static Tin–Manganese Battery with 30000-Cycle Lifespan Based on Stabilized Mn3+/Mn2+ Redox Chemistry

X Li, Y Tang, C Han, Z Wei, H Fan, H Lv, T Cai, Y Cui… - ACS …, 2023 - ACS Publications
High-potential Mn3+/Mn2+ redox couple (> 1.3 V vs SHE) in a static battery system is rarely
reported due to the shuttle and disproportionation of Mn3+ in aqueous solutions. Herein …

Electronic effects of metal hexacyanoferrates: An XPS and FTIR study

SJ Gerber, E Erasmus - Materials Chemistry and Physics, 2018 - Elsevier
A series four metal hexacyanoferrates, with a general formula of K x M y [Fe (CN) 6] z· qH 2
O, with x, y, z and q representing stoichiometric numbers and M= Fe (1), Co (2), Ni (3) and …

[HTML][HTML] Review of the structure of tris (β-diketonato) manganese complexes

J Conradie, CR Ohoro, JF Amaku, KO Oyedotun… - Journal of Molecular …, 2023 - Elsevier
This review present the reported experimental structures and theoretically calculated
structures of tris (β-diketonato) manganese complexes. Experimental high spin tris (β …

Significance of the electron-density of molecular fragments on the properties of manganese (iii) β-diketonato complexes: an XPS and DFT study

R Gostynski, J Conradie, E Erasmus - RSC advances, 2017 - pubs.rsc.org
DFT and XPS studies were conducted on a series of nine manganese (III) complexes of the
general formula [Mn (β-diketonato) 3], with the ligand β-diketonato= dipivaloylmethanato (1) …

Silica Nanopowder Supported Frustrated Lewis Pairs for CO2 Capture and Conversion to Formic Acid

K Mentoor, L Twigge, JWH Niemantsverdriet… - Inorganic …, 2020 - ACS Publications
Treatment of hydroxylated silica nanopowders S1 and allyl-functionalized silica
nanopowders S2 with 3-(diphenylborano)-or 3-bis (pentafluorophenylborano) …

XPS photoelectron lines, satellite structures and Wagner plot of Cu (II) β-diketonato complexes explained in terms of its electronic environment

J Conradie, E Erasmus - Journal of Electron Spectroscopy and Related …, 2022 - Elsevier
A series of copper (II) β-diketonato complexes [Cu (R 1 CHCOCHR 2) 2], with R 1= R 2= C 6
H 5 (1); R 1= C 6 H 5 and R 2= CH 3 (2); R 1= R 2= CH 3 (3); R 1= C 6 H 5 and R 2= CF 3 …

Providing fundamental and applied insights into Fischer–Tropsch catalysis: Sasol–Eindhoven University of Technology collaboration

J van de Loosdrecht, IM Ciobica, P Gibson… - ACS …, 2016 - ACS Publications
Although Fischer–Tropsch synthesis (FTS) was discovered more than 90 years ago, it
remains a fascinating topic, having relevance from both an industrial and academic …

Photocatalytic decomposition of an azo dye using transition-metal-doped tungsten and molybdenum carbides

BP Mabuea, HC Swart, E Erasmus - ACS omega, 2022 - ACS Publications
The preparation, characterization, and photocatalytic application of tungsten or molybdenum
carbides (Ni-WC, 1, Co-WC, 2, Ni-MoC, 3, Co-MoC, 4, NiCo-WC, 5, NiCo-MoC, 6, NiFe-WC …

Stereoselective synthesis of the isoxazolidine ring via manganese (iii)-catalysed aminoperoxidation of unactivated alkenes using molecular oxygen in air under …

D Yamamoto, I Hirano, Y Narushima, M Soga… - Green …, 2022 - pubs.rsc.org
In this study, we developed a route for the tris (mono-ferrocene-functionalised β-diketonato)
manganese (III)-complex catalysed diastereoselective oxygenative aminoperoxidation of …